Thermoelectric efficiency is determined by the figure of merit (ZT) with the achievement of high electrical conductivity (σ), high Seebeck coefficient (S), and low thermal conductivity (k) for high performance thermoelectric devices. Tungsten disulfide (WS 2 ) has been reported to have a comparably high S (3.5 × 10 2 ∼9.5 × 10 2 μV/K) and low σ (10 −2 −10 −1 S/m), which leads to a low ZT value (approximately 0). In this study, WS 2 particles were hybridized with highly conductive reduced graphene oxide (rGO) particles (∼10 5 S/m). The inclusion of rGO provides conductive paths for the transfer of carriers in the composites, and thus, this led to an increase in σ (∼3 × 10 3 S/m). The hybrid material of WS 2 /rGO, as a function of the weight percentage of rGO, was fabricated by spark plasma sintering. As a result, the power factor in a WS 2 / 0.8 wt % rGO (87 μW/mK 2 ) with enhanced σ was 310% greater than that of WS 2 . Moreover, two-dimensional structures of the materials contributed to the induction of phonon scattering and resulted in steady k in spite of enhanced σ with increased rGO content. Consequently, an optimized ZT value was obtained for the WS 2 /0.8 wt % rGO sample; this value was 260% greater (approximately 6.8 × 10 −4 ) than that of WS 2 without rGO (approximately 1.9 × 10 −4 ).