Inhibitory effect of 2-Nitroacridone on corrosion of low carbon steel in 1 M HCl solution: An experimental and theoretical approach

Aslam, Jeenat; Aslam, Ruby; Lone, Irfan H.; Radwan, Nagi R.E.; Mobin, Mohammad; Aslam, Afroz; Parveen, Mehtab; Alfreedi, Ajab A.; Alzulaibani, Alaa Awad

doi:10.1016/j.jmrt.2020.02.033

Cited by 39 publications

(17 citation statements)

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“…PDP and EIS measurements were used to assess the degree of surface coverage (Θ) as a function of the inhibitor concentration (C), which was graphically tested by fitting it with several isotherms to ensure the best fits that are described in this research. 72,73 The best way to describe CO-GO adsorption on carbon steel was found for the Langmuir adsorption isotherm. This isotherm could be expressed as 74,75 θ = + C K C 1 ads (10) where Θ is the degree of surface coverage, C inh is the concentration of inhibitors, and K ads symbolizes the equilibrium adsorption constant, which is graphically calculated from the plot displayed in Figure 7.…”

Section: ■ Results and Discussionmentioning

confidence: 99%

“…Supposing that the inhibitor’s inhibition efficiency is primarily because of the deposited molecules’ inhibiting impact, the values were estimated using the inhibition efficiency obtained from PDP and EIS measurements using eqs and Various isothermal adsorptions, including Frumkin, Temkin, Freundlich, and Langmuir, have been tried to appropriate the value of (Θ). PDP and EIS measurements were used to assess the degree of surface coverage (Θ) as a function of the inhibitor concentration ( C ), which was graphically tested by fitting it with several isotherms to ensure the best fits that are described in this research. , The best way to describe CO-GO adsorption on carbon steel was found for the Langmuir adsorption isotherm. This isotherm could be expressed as , where Θ is the degree of surface coverage, C inh is the concentration of inhibitors, and K ads symbolizes the equilibrium adsorption constant, which is graphically calculated from the plot displayed in Figure .…”

Section: Resultsmentioning

confidence: 99%

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Performance Evaluation of New Chalcone Oxime Functionalized Graphene Oxide as a Corrosion Inhibitor for Carbon Steel in a Hydrochloric Acid Solution

et al. 2022

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This study aims to synthesize new chalcone oxime functionalized graphene oxide (CO-GO) and investigate the enhancement in corrosion protection. The morphology and structure of the synthesized CO-GO have been characterized by elemental analysis: Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM). Moreover, the effectiveness of corrosion inhibition was investigated by utilizing electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP). The results of the above analyses demonstrate that CO-GO has an outstanding corrosion inhibitor performance of up to 94% and acts as a mixed-type inhibitor with a primarily anodic action. The effect of temperature on a carbon steel surface indicates that the tested composites are chemisorbed. A few techniques were able to provide surface characterization such as scanning electron microscopy and ultraviolet (UV)−visible spectroscopy to confirm inhibitor adsorption on the carbon steel surface.

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Section: ■ Results and Discussionmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Performance Evaluation of New Chalcone Oxime Functionalized Graphene Oxide as a Corrosion Inhibitor for Carbon Steel in a Hydrochloric Acid Solution

et al. 2022

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“…AFM can obtain high-resolution images of the sample surface and its roughness. A lower roughness of a metal surface indicates lower corrosion products and higher protection [39,40]. The 3D and 2D topography maps of copper in blank and inhibited (ATZD) solutions are represented in Figure 6.…”

Section: Atomic Force Microscopymentioning

confidence: 99%

Corrosion Inhibition Properties of Thiazolidinedione Derivatives for Copper in 3.5 wt.% NaCl Medium

Lgaz

Saha

Lee

et al. 2021

Metals

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Copper is the third-most-produced metal globally due to its exceptional mechanical and thermal properties, among others. However, it suffers serious dissolution issues when exposed to corrosive mediums. Herein, two thiazolidinedione derivatives, namely, (Z)-5-(4-methylbenzylidene)thiazolidine-2,4-dione (MTZD) and (Z)-3-allyl-5-(4-methylbenzylidene)thiazolidine-2,4-dione (ATZD), were synthesized and applied for corrosion protection of copper in 3.5 wt.% NaCl medium. The corrosion inhibition performance of tested compounds was evaluated at different experimental conditions using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization curves (PPC) and atomic force microscopy (AFM). EIS results revealed that the addition of studied inhibitors limited the dissolution of copper in NaCl solution, leading to a high polarization resistance compared with the blank solution. In addition, PPC suggested that tested compounds had a mixed-type effect, decreasing anodic and cathodic corrosion reactions. Moreover, surface characterization by AFM indicated a significant decrease in surface roughness of copper after the addition of inhibitors. Outcomes from the present study suggest that ATZD (IE% = 96%) outperforms MTZD (IE% = 90%) slightly, due to the presence of additional –C3H5 unit (–CH2–CH = CH2) in the molecular scaffold of MTZD.

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“…Literature study reveals that several reports are available describing the anticorrosion effect of amino acids 5 , 6 , biopolymers 7 , 8 , plant extracts 9 , 10 , rare earth metals 11 , organic compounds such as drugs 12 , 13 , surfactants 14 , and ionic liquids 15 on metals and alloys. The main disadvantage of using plant materials as corrosion inhibitors is their instability; and readily biodegradability.…”

Section: Introductionmentioning

confidence: 99%

Novel ZrO2-glycine nanocomposite as eco-friendly high temperature corrosion inhibitor for mild steel in hydrochloric acid solution

Aslam

Mobin

Shoeb

et al. 2022

Sci Rep

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We report the green synthesis of novel ZrO2-Glycine nanocomposite referred to as ZrO2-Gly NC followed by its characterization using X-ray diffraction (XRD), Fourier transforms infrared (FT-IR) spectroscopy, SEM/EDX, and transmission electron microscopy (TEM) techniques. Further, the inhibition effect of the varying concentration of ZrO2-Gly NC on the corrosion of mild steel (MS) in 1 M HCl was investigated by weight loss and electrochemical measurements at 40–80 °C. The percentage inhibition efficacy of NC increased with the increase of concentration and temperature and reached about 81.01% at 500 ppm at 70 °C which decreased at 80 °C and exhibited 73.5% inhibition efficiencies. According to the polarization measurements, the investigated ZrO2-Gly NC works as a mixed-type inhibitor with predominantly inhibiting cathodic reaction. Also, the adsorption isotherm analysis indicated that the adsorption was spontaneous and followed the Langmuir adsorption isotherm. Furthermore, the contact angle measurement revealed the water-repelling property of the investigated inhibitor. The surface morphological study via SEM–EDS micrograph affirmed the appearance of a smooth surface in presence of inhibited media suggesting the formation of protective film by the adsorption of ZrO2-Gly NC on the surface of the MS even at higher temperature.

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Inhibitory effect of 2-Nitroacridone on corrosion of low carbon steel in 1 M HCl solution: An experimental and theoretical approach

Cited by 39 publications

References 68 publications

Performance Evaluation of New Chalcone Oxime Functionalized Graphene Oxide as a Corrosion Inhibitor for Carbon Steel in a Hydrochloric Acid Solution

Performance Evaluation of New Chalcone Oxime Functionalized Graphene Oxide as a Corrosion Inhibitor for Carbon Steel in a Hydrochloric Acid Solution

Corrosion Inhibition Properties of Thiazolidinedione Derivatives for Copper in 3.5 wt.% NaCl Medium

Novel ZrO2-glycine nanocomposite as eco-friendly high temperature corrosion inhibitor for mild steel in hydrochloric acid solution

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