“…Being solid-state energy conversion technique, it has advantages of reliability, simplicity, lightweight, compactness, and environmental friendliness [1,3]. To make TE technology feasible, it requires significant improvement in conversion efficiency (η), which is jointly determined by the Carnot efficiency and the dimensionless figure of merit [4], 𝑧𝑇 = 𝑆 2 𝑇/(𝑘 𝐿 + 𝑘 𝐸 ), where S is the Seebeck coefficient, is the electrical conductivity, T is the absolute temperature, and k L and k E are the lattice and electronic thermal conductivities, respectively. Improving zT of a TE material by simultaneous optimization of transport parameters is a major fundamental challenge since these parameters are heavily interdependent [5][6][7][8][9][10][11].…”