In this study, a method for estimating the exponent “n” values of the catchment-area equations of four sub-basins within the poorly gauged Benin-Owena River Basin Development Authority (BORBDA) in Nigeria is presented to enable the estimation of flows at ungauged sites within the basin and the determination of small hydropower (SHP) potential at different locations in each sub-basin and the entire basin. Optimal prediction of streamflow characteristics in poorly gauged basin requires developing a methodology for extrapolation of data from gauged to ungauged sites within the basin. Four sub-catchments of BORBDA, a poorly gauged basin in Nigeria, were investigated using Remote Sensing (RS), Geographic Information System (GIS), statistical techniques, and Natural Resources Conservation Service-Curve Number (NRCS-CN) hydrological model. Discharge values at gauged sites (Qg) were obtained from recorded discharge values collected for 12 months at an established gauging station in each sub-basin. RS and GIS techniques were used to develop classification maps and obtain crucial data like curve number (CN), elevation, Hydrologic Soil Group (HSG), rainfall intensity, slope, area of gauged and ungauged required for evaluating spatial discharge (ungauged) utilizing NRCS-CN model. From the established model for each sub-basin, exponent “n” in the relationship between discharge and catchment area was obtained to be 0.23, 0.41, 0.71, and 0.74. Using the lumped modeling approach, which considers a watershed as a single unit for computation, where watershed parameters and variables were to be averaged produced “n” = 0.52 for BORBDA area, which is within the range of 0.5–0.85 suggested by previous researchers. Obtained BORBDA exponent “n” was validated for use in the entire basin through soil homogeneity test by generating BORBDA soil map which confirms the four sub-basins investigated share similar HSG A, B, and D with BORBDA. The exponent “n” value is useful for predicting flows in ungauged parts of the basin. The exponent “n” value obtained for the basin is helpful in the assessment of discharge and determination of SHP potential at different locations within the poorly gauged BORBDA basin, and the dissemination of the research findings will find practical use and guide to practicing hydrologists in Nigeria and locations around the world with similar challenges of poorly gauged basins particularly Africa and other developing countries.