2001
DOI: 10.1023/a:1012827413518
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Cited by 39 publications
(48 citation statements)
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“…It was reported that PVA could not act as a reducing agent without any irradiation but worked as a good reducing agent under photoirradiation by generating radical species [43]. Mills' group reported earlier on the formation of metallic particles during photoirradiation in the presence of PVA [44]. Using our method, we believe that radical species or solvated electrons formed during the photoirradiation of PVA are responsible for the reduction of Ag + to Ag(0).…”
Section: Reaction Mechanisms Of Pva-ag Nanowires Synthesismentioning
confidence: 76%
“…It was reported that PVA could not act as a reducing agent without any irradiation but worked as a good reducing agent under photoirradiation by generating radical species [43]. Mills' group reported earlier on the formation of metallic particles during photoirradiation in the presence of PVA [44]. Using our method, we believe that radical species or solvated electrons formed during the photoirradiation of PVA are responsible for the reduction of Ag + to Ag(0).…”
Section: Reaction Mechanisms Of Pva-ag Nanowires Synthesismentioning
confidence: 76%
“…Absorptions peaks centered between 270 and 300 nm are in place of those related to nanoparticles and can be assigned to different clusters of silver ions such as Ag + , Ag +2 , Ag +3 [33][34][35]. This means that the majority of Ag + ions chemically interact with the dilute acetic acid and form CS/silver acetate as a source of silver ions [27].…”
Section: Uv-vis Spectroscopy Analysismentioning
confidence: 99%
“…The preparation of silver “nano-dispersion” directly in the PVA matrix by a one-step method based on the reduction of the inorganic precursor through a solid state synthesis has been achieved by thermal annealing [130] and UV irradiation [131,132,133], which result very efficient methodologies because they take advantage on the formation of a complex between the PVA matrix and the silver nitrate: Ag + ions can be easily chelated by the hydroxyl groups of the polymer and then reduced directly in the host matrix.…”
Section: Noble Metal Nanoparticles (Nmnp) Thermoplastic Polymer Sementioning
confidence: 99%