1997
DOI: 10.1021/ic961375h
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Kinetics of the Aquation of Amminepentacyanoferrate(II). A Volume Profile Analysis

Abstract: The kinetics of the aquation and reverse formation reactions of Fe(CN)5NH3 3- were studied in detail. The reported activation parameters and volume profile strongly support the operation of a limiting D substitution mechanism.

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Cited by 25 publications
(26 citation statements)
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“…In all cases, the rate of the Fe complex decomposition process was found to be independent of the iron and pyrazine concentrations, as expected for a fully dissociative mechanism. [3,4,[37][38][39] These values are in excellent agreement with those previously published. [40,41] Figure 3 displays the typical trends observed for the values of k obs with excess concentration of the different compounds involved.…”
Section: Introductionsupporting
confidence: 92%
“…In all cases, the rate of the Fe complex decomposition process was found to be independent of the iron and pyrazine concentrations, as expected for a fully dissociative mechanism. [3,4,[37][38][39] These values are in excellent agreement with those previously published. [40,41] Figure 3 displays the typical trends observed for the values of k obs with excess concentration of the different compounds involved.…”
Section: Introductionsupporting
confidence: 92%
“…1-Benzoylethylpyridinium-4-aldoxime chloride (BEPA-4) was prepared by mixing equimolar solutions of chloropropiophenone and pyridine-4-aldoxime [5,6] [7] and were freshly prepared. Ionic strength was maintained constant with sodium chloride.…”
Section: Methodsmentioning
confidence: 99%
“…Amminepentacyanoferrate(II) easily hydrolyses in aqueous solutions [91] [Eq. (1)] and reacts with thioethers yielding stable thioether complexes [Eq.…”
Section: Formation Redox Properties and Chemisorption Of Pentacyanotmentioning
confidence: 99%