Kristallstruktur von Dichlormethylsulfonium‐hexafluoroarsenat

Abstract

Dichlormethylsulfonium‐hexafluoroarsenat kristallisiert in der monoklinen Raumgruppe P21/c mit a = 867,5(9) pm, b = 792,7(5) pm, c = 1200,8(10) pm, β = 96,99(8)°, Z = 4. Durch drei kurze interionische Schwefel‐Fluor‐Kontakte ergibt sich eine verzerrt oktaedrische Koordination am Schwefel. Weiterhin werden im Festkörper Chlor‐Fluor‐Kontakte beobachtet.

Polyvalent perfluoroorgano- and selected polyfluoroorgano-halogen(III and V) compounds

“…Thus, the salt [CF 3 (CH 3 )I][MF 6 ] was obtained by the electrophilic methylation of CF 3 I with CH 3 F and MF 5 in SO 2 (Eq. (24a)) [50]. Mono-and di-methylation of 1,4-diiodotetrafluorobenzene occurred similarly (Eq.…”

Über die Darstellung der (Chlorthio)sulfoniumsalze [(CH3)2SSSCl]+SbF6 -, [(CH3)2SSCl]+SbF6 - und des isomeren [(CH3)(Cl)S – SCH3]+SbCl6 - / On the Preparation of the (Chlorothio)sulfonium Salts [(CH3)2SSSCl]+SbF6-, [(CH3)2SSCl]+Minkwitz1, Kornath2, Krause3 et al. 1990Zeitschrift Für Naturforschung B8000View full textAdd to dashboardCite

“…Sie w ur de in den bisher untersuchten K ationen zwischen 194,9 pm im SCl3+AsF6~ [19] und 197,8(2) im C H 3SC12+AsF6" [20] gemessen. Der o.g.…”

Heterocations in Superacid Systems

“…107,[352][353][354][355] There are two general methods for the preparation of dialkylhalonium ions. Dialkylhalonium ions were first observed as stable fluoroantimonates and characterized by Olah and DeMember 333 in 1969.…”

“…99 (Trimethylsilyl)methylhalonium ions 134 have also been obtained under stable ion conditions and characterized by 1 H, 13 C, and 29 Si NMR spectroscopy. Minkwitz and Gerhard 355 have reported the synthesis of the AsF 6 À and Sb 2 F 11 À salts of cation 129 (X ¼ Br) by reacting bromine with CH 3 OSO þ MF 6 À (M ¼ As, Sb). Minkwitz and Gerhard 355 have reported the synthesis of the AsF 6 À and Sb 2 F 11 À salts of cation 129 (X ¼ Br) by reacting bromine with CH 3 OSO þ MF 6 À (M ¼ As, Sb).…”

“…(4.103)] but failed to prepare the analogous bromonium compound 356. (4.103)] but failed to prepare the analogous bromonium compound 356.…”