In many regions of the world, the winter period is a time of poor air quality, due primarily to the increased use of individual and district heating systems. As a consequence, the atmospheric air contains increased concentrations of both particulate matter and gaseous pollutants (as a result of “low” emissions at altitudes of up to 40 m and “high” emissions more than 40 m above ground level). In winter, the increased pollution is very often exacerbated by meteorological conditions, including air temperature, pressure, air speed, wind direction, and thermal inversion. Here, we analyze the concentrations of particulate matter (PM10, PM2.5, and PM1.0) and gaseous pollutants (H2S, SO2, and VOC) in the immediate vicinity of a large solid fuel-fired heat and power plant located in an urban agglomeration. Two locations were selected for analysis. The first was close to an air quality measurement station in the center of a multi-family housing estate. The second was the intersection of two main communication routes. To determine the impact of “low” and “high” emissions on air quality, the selected pollutants were measured at heights of between 2 and 50 m using an unmanned aerial vehicle. The results were compared with permissible standards for the concentration of pollutants. Temperature inversion was found to have a strong influence on the level of pollutants at various heights, with higher concentrations of particulate matter registered at altitudes above 40 m. The source of PM, H2S, and SO2 pollutants was confirmed to be “low emission” from local transport, industrial plant areas, and the housing estate comprising detached houses located in the vicinity of the measuring points. “High emission” was found to be responsible for the high concentrations of VOC at altitudes of more than 40 m above the intersection and in the area of the housing estate.