The effect of ambient gas on the expansion dynamics of the plasma generated by laser ablation of an aluminum target has been investigated using frequency doubled radiation from a Q-switched Nd:YAG laser. The diagnostic tools include fast photography of overall visible plume emission using a 2 ns gated intensified charged coupled device and space and time resolved emission spectroscopy using a 50 cm monochromator/spectrograph and photomultiplier tube. The expansion behavior of the plasma was studied with ambient air pressure ranging from 10 Ϫ6 to 100 Torr. Free expansion, plume splitting and sharpening, hydrodynamic instability, and stagnation of the plume were observed at different pressure levels. Space and time resolved emission spectroscopic studies showed a twin peak distribution for Al and Al ϩ species at farther distances illustrating plume splitting at pressures higher than 100 mTorr. Combining imaging together with time resolved emission diagnostics, a triple structure of the plume was observed. The expansion of the plume front was compared with various expansion models and found to be generally in good agreement.