The properties of InSb∕AlxIn1−xSb quantum-well light-emitting diodes have been investigated as a function of temperature from 300to15K. Over the whole range, the peak emission occurred at significantly higher energies than the band gap of InSb but below the band gap of the AlxIn1−xSb barriers, confirming that emission is from the quantum wells. Maximum internal quantum efficiencies of 65% and 85% were measured at 15K for diodes containing 40 and 20nm quantum wells, respectively.