Light emission from metal−insulator−semiconductor junctions (MISJs) has been explored for decades as a possible on-chip light source; however it is not clear whether the mechanism of light emission is plasmonic in nature or is dominated by electroluminescence. Previous studies only investigated silicon with low doping levels, but here we show that only highly doped silicon allows us to excite surface plasmon polaritons (SPPs) in MISJs via inelastic tunneling. This paper describes the mechanism of charge transport and light emission from siliconbased Au-SiO 2 -nSi MISJs as a function of the doping level N d varying from 1.6 × 10 15 cm −3 to 1.0 × 10 20 cm −3 . At low doping levels (N d ∼ 10 15 cm −3 ), the MISJs behave as Schottky diodes, and the mechanism of light emission involves a radiative recombination of electrons and holes from minority carrier injection under high applied bias (>5.5 V). With increasing doping levels, the current−voltage characteristics of the MISJs change, resulting in symmetrical current−voltage curves with parabolic conductance behavior characteristic of quantum mechanical tunneling. MISJs with the highest doping level (N d ∼ 10 20 cm −3 ) are dominated by quantum mechanical tunneling, and light emission originates from radiative decay of surface plasmon polaritons (SPPs) via scattering at threshold voltages as low as 1.5 V. Our simulations indicate that tunneling over the thin SiO 2 barrier between the Au and highly doped nSi excites a hybrid-SPP mode localized to the Au whose dispersion depends on the effective index induced by the SiO 2 −nSi interface. Our studies show that Si needs to be sufficiently doped to be conductive enough to enable SPP excitation via inelastic tunneling.