IntroductionInformation technology is an area of such broad importance that even small enhancements to existing methodologies can be useful. Most information derived from chemistry -and especially from some form of analysis -proceeds by a path in which a sensor (e.g., an analytical instrument), using electrical power, generates information, which is then encoded and transmitted in a separate step, again using electrical power, to a separate unit (which may be local or distant) for processing and interpretation. We [1,2] and others [3][4][5][6] are exploring schemes in which information is transmitted directly, without using electrical energy. Such schemes have the potential to be useful where electrical power is not reliably available, or where other constraints (e.g., size) argue for other types of solutions.Infofuses are a new system for non-electronic communications that uses the multiplexing of frequencies enabled by chemistry. [1,2] This paper describes non-binary encoding schemes for infofuses which allow a single pulse of light to encode each of the alphanumeric characters. This work demonstrates a physical implementation of a new, information-dense, encoding scheme, and is important to materials scientists and engineers interested in research at the interface between information science and chemistry. We refer to this area as infochemistry.We consider an elementary system for transmitting information to have seven steps: i) Assembling the message (either by writing it, or by collecting it from a sensor), ii)Encoding the information in a form that can be transmitted, iii) Transmitting the information,
3/18Infochemical systems offer the opportunity to implement, in a physical system, encoding schemes that are more information-dense than simple binary by transmitting information optically using multiple (rather than two) states (e.g., multiple intensities and multiple wavelengths). Multiple-state pulses can give a higher density of information per clock cycle (although at increased complexity, with increased error rates, and lower bit rate) than the binary systems now almost universally used. [7,8] We have developed two infochemical systems that use chemical interactions and reactions (and that do not require electrical power in the transmission step) to transmit encoded messages as optical pulses. One is based on strips of flammable polymer (nitrocellulose) with thermally emissive salts (infofuses) patterned onto it. [1,2] The second is a microfluidic device that shutters light (a droplet shutter), and capitalizes on the high frequency stability of the rate of generating bubbles by a flow-focusing nozzle. [9] In this latter system, the combination of optically transparent droplets and windows serve as optical shutters to encode information.Upon ignition of one end of an infofuse, the flame front (at a temperature of ~ 1000°C) propagates along the fuse at a constant rate (2 -3 cm/s in the systems we use). As this propagating hot zone reaches each spot of thermally emissive salts, it emits light at waveleng...