Metal-insulator-metal (MIM) capacitors withAl/HfO 2 /La 2 O 3 /Al structure were fabricated using pulse laser deposition for the first time and were further investigated for their electrical and morphological properties. The MIM capacitors for future applications in analog/mixed signal circuits need further improvement in their electrical characteristics. We have fabricated MIM capacitors having low leakage current density of ∼ 9.6 × 10 −9 A/cm 2 at −1 V and high-capacitance density ∼20.8 fF/μm 2 at 3.5 V for 100-Hz frequency. The frequency dispersion effect of these MIM capacitors is observed to be quite small. We have also obtained an improved voltage coefficient of capacitance of ∼101 ppm/V 2 at 1 MHz along with improved dielectric constant which is one of the most important parameters for next generation MIM capacitors. The physical thickness of HfO 2 /La 2 O 3 dielectric film stack is found to be 13 nm in cross-section TEM. This value of physical thickness is consistent with the low EOT ∼1.66-nm estimated using C-V curve. Morphological studies of having nanostructured film morphology with low roughness are consistent with the electrical characteristics of MIM capacitors. Further improvement in electrical properties like lower leakage current density, etc., has been obtained in post metallic annealed MIM capacitors. We have observed Schottky emission as the dominant current conduction mechanism for these MIM capacitors.
Index Terms-Dielectric constant, HfO 2 , high-κ dielectric, La 2 O 3 , MIM capacitor, voltage coefficient of capacitance.1536-125X India. His current research interests include fabrication of nanomaterials using plasma methods and their characterization for optical and electrical applications. He is also working on the fabrication of high-k dielectrics using plasma methods and study their various properties for possible use in next generation metal-oxide-semiconductor and metal-insulator-metal capacitors.V. Gupta (SM'01) received the B.Sc., M.Sc., and Ph.D. degrees in physics in 1987, 1989, and 1995, from the University of Delhi, Delhi, India.In 1995, he was a Reader in Physics at Deendayal Upadhyaya College, University of Delhi. He is currently a Professor in the Department of Physics and Astrophysics, University of Delhi. He received BOYSCAST fellow and MRSI medal. His current research interests include piezoelectric, ferroelectric, multiferroics and semiconducting thin films, gas/ bio sensors, UV photon detector, electro-optic applications, surface plasmon resonance, oxide nanostructures for multifunctional applications, etc. He is also working on the fabrication of MEMs-based microheaters, microwave resonators, surface acoustic wave devices, etc., and their respective applications.