The switching layer with SiGeO x /SiGeON structure is investigated to improve the electrical characteristics of resistive nonvolatile memory. A bipolar resistance switching behavior owning inferior stability was observed in Pt/SiGeO x /TiN memory cells. To obtain practical memory, a convenient and compatible SiGeON ($5 nm) is introduced at SiGeO x /anode interface to stabilize the disruption length of filaments near anode electrode. Compared with Pt/SiGeO x /TiN memory cells, the proposed Pt/SiGeO x / SiGeON/TiN cells is effective at minimizing the dispersions of memory switching parameters.Resistance random access memory (RRAM) composed of an insulating layer sandwiched by two electrodes has recently attracted great attention for replacement of flash memory in the next-generation nonvolatile memory applications. Up to now, the resistance switching effect has been observed in various materials including perovskite oxides, 1 chalcogenide materials, 2 and oxide materials such as SiO, ZnO, NiO, and TiO 2 . 3-8 Among these materials, oxide materials are most widely investigated and the resistance switching is generally considered as a result of the formation/rupture of the localized conducting filament. 1 To improve the switching behaviors, some methods have been proposed to stabilize the location of filament formation, such as doping Gd in TiO 2 film, 9 and embedding metal nanocrystals in the switching layer. 10 Other researches use different material to form the bi-layer which changes the crystal lattice or oxygen ion/vacancy concentration of the material interface to confine the filament. [11][12][13][14][15] In this study, the SiGeO x film was taken as the resistive switching layer in Pt/SiGeO x /TiN memory cells because germanium and silicon are extremely compatible with the prevalent complementary metal oxide semiconductor (CMOS) process. Nevertheless, these devices would get stressed from switching cycling and become unstable causing fluctuations in resistance states. Hence, a compatible SiGeON layer is proposed to be inserted between SiGeO x and TiN to control the disruption length of filaments to enhance memory switching parameters. It is a simple method to enhance the resistance switching parameters which introduce only ammonia in the manufacturing process. The best merit of this method is that the bi-layer structure is composed of the unitary material.The memory cells were fabricated as follows: For signal switching layer, a 30-nm-thick SiGeO x film was deposited on TiN/SiO 2 /Si substrate by RF magnetron sputter deposition system using a Si 0.45 Ge 0.15 O 0.4 target. The sputtering was carried out with a RF power of 100 W at room temperature, in Ar/O 2 ¼ 30 sccm/10 sccm mixed gas ambient with a working pressure of 4 mTorr. Similarly, for double switching layer, the 5-nm-thick SiGeON and 25-nm-thick SiGeO x films were sequentially deposited on TiN/SiO 2 /Si substrate, in Ar/NH 3 ¼ 30 sccm/10 sccm and Ar/O 2 ¼ 30 sccm/10 sccm mixed gas ambient, respectively. Finally, all samples were capped with 80-nm-thick...