Organic field-effect transistors
(OFETs) have opened up new possibilities
as key elements for skinlike intelligent systems, due to the capability
of possessing multiple functionalities. Here, multifunctional OFET
devices based on gelatin, a natural biopolymer gate dielectric, and
TIPS-pentacene as an organic semiconductor are extensively explored.
Gelatin is combined with a thin high-k HfO2 dielectric layer deposited by atomic layer deposition (ALD) to achieve
a low leakage current and low-voltage operation. The natural biopolymer
offers a better semiconductor:dielectric interface, leading to better
charge conduction in the devices, along with an enhancement of sensing
capabilities giving additional functionality. These fabricated flexible
OFET devices exhibit excellent electrical characteristics with a high
field-effect mobility reaching over 2 cm2/(V s) (extracted
with C
i at 1 kHz), a low subthreshold
swing (SS) of ∼200 mV/dec, and a high current on–off
(I
on/I
off)
ratio at a low operating voltage of −5 V with excellent electrical
and mechanical stability. Moreover, circuit and multiparameter sensing
capabilities for visible and UV light, as well as for humidity and
breath rate, have been successfully demonstrated for these devices.
Our results indicate that these multifunctional OFET devices can open
up a plethora of opportunities for practical applications such as
real-time health and environmental monitoring.