Magnetic Interactions as Supramolecular Function: Structure and Magnetic Properties of Hydrogen-Bridged Dinuclear Copper(II) Complexes

Synthesis, Structures and Magnetic Properties of Hydrogen-bond Directed 2D Heterobimetallic Cyanide-bridged Coordination Polymers

“…23,[28][29][30] The magnetic susceptibility data for these two complexes were simultaneously fitted by full-matrix diagonalisation of the following spin Hamiltonian: 31 23,[28][29][30] The magnetic susceptibility data for these two complexes were simultaneously fitted by full-matrix diagonalisation of the following spin Hamiltonian: 31…”

Use of Pyrazole Hydrogen Bonding in Tripodal Complexes to Form Self Assembled Homochiral Dimers

“…There are other examples of complexes that exhibit some of these features individually. A copper Schiff base dimer is held together by hydrogen bonding but lacks the other structural elements [48]. The π-π stacking feature is observed in imidazole based supramolecular complexes of manganese(II) and cobalt(II) [49].…”

Selectivity of a thiosemicarbazonatocopper(ii) complex towards duplex RNA. Relevant noncovalent interactions both in solid state and solution

“…38 Other possible pathway for exchange coupling would be the hydrogen bonding that relates the closest Cu1A and Cu1B centres in 5. The presence of even relatively intense magnetic coupling in hydrogen bonded Cu(II)-monomeric compounds has been discussed both in experimental 39 and theoretical studies. 40 Taking into account the presence of weak antiferromagnetic coupling in 5 despite the very short Cu···Cu distance in its structure, we suggest that the magnetic interactions in 1, clearly stronger than those in 5, are mainly intradinuclear in nature.…”