A wireless power transfer (WPT) system can bring convenience to human life, while a leakage magnetic field around the system can be harmful to humans or the environment. Due to application limitations of aluminum and ferrite materials, it is urgent to find a new type of shielding material. This paper first proposes a detailed model and analysis method of the matrix shielding metamaterial (MSM), which is applied to the low-frequency WPT system in an electric vehicle (EV). The MSM is placed on the top and side of the EV system to shield the magnetic field from all positions. To explore its function, a theoretical analysis of the MSM is proposed to prove the shielding performance. The simulation modeling and the design procedure of the MSM are introduced. Moreover, the prototype model of the WPT system with the MSM is established. The experimental results indicate that the magnetic field is controlled when the MSM is applied on the top or side of the EV-WPT system. The proposed MSM has been successfully proven to effectively shield the leakage magnetic field in the WPT system, which is suitable for the kHz range frequency.