Pure electric vehicles provide an enticing ecofriendly alternative to traditional fossil fuel combustion engine locomotives. Batteries have primarily been used to store energy in electric vehicles; however, peak load demand and transient power leading to decreased battery lifespan have bred interest in hybrid energy storage systems in electric vehicles. Management of energy drawn from a hybrid energy storage system (HESS) in electric vehicles is a real-time multistage optimization problem aimed at minimizing energy consumption while aptly distributing energy drawn from the battery and capacitor to enhance the battery life cycle. This paper explores the feasibility of a master-slave salp swarm optimization algorithm (MSSSA) (metaheuristic algorithm) in a HESS control strategy for electric vehicles. Introducing a master-slave learning approach to the salp swarm algorithm (SSA) improves its performance by increasing its convergence rate while maintaining a balance between exploration and exploitation phases of the algorithm. A comparison of the MSSSA results with the SSA (salp swarm algorithm), DA (dynamic algorithm), WOA (whale optimization algorithm), MFO (moth flame optimization algorithm), GA (genetic algorithm), and PSO (particle swarm optimization algorithm) on benchmark test functions and dynamic program simulation of an electric vehicle’s HESS control strategy and shows preeminence of the MSSSA control strategy for HESS.