We study the ratio of fragmentation fractions, f b / f b , from the measurement of 0 b → + c π − and 0 b → + c π − with + c / + c → pK − π +. With the branching fraction B(+ c → pK − π +) = (2.2 ± 0.8)% obtained under the U-spin symmetry, the fragmentation ratio is determined as f b / f b = 0.054 ± 0.020. To reduce the above uncertainties, we suggest to measure the branching fractions of + c → pK * 0 and + c → + K * 0 at BESIII, Belle II and LHCb.