The paper presents an attempt to use milled waste of carbon fiber reinforced polymer (rCFRP) laminates as fillers for polyester resin. The obtained polyester-rCFRP composites were tested for technological, mechanical and frictional properties. It was found that the viscosity increased for the compositions containing rCFRP particles in comparison to the neat resin. Flexural strength improved in comparison to the neat resin, but only for the composites filled with a fraction containing particles below 0.2 mm in diameter and a mixed-diameter particles fraction. For composites containing the above-mentioned fractions, a significant reduction in the dynamic friction coefficient and a reduction in wear (the weight loss after friction test) were found. The obtained results indicate the advisability of further research and optimization of this new type of composites in terms of frictional applications.