To follow the effect
of the microwave heating path on the structure
of coal, eight 50 mm diameter, 30 mm long dry coal cores from the
same coal seam with similar pore structure characteristics were microwave-treated
using 4 pathways. The T
2 spectrum, pore-volume,
temperature, mass, and visual changes of coal samples were analyzed
before and after microwave heating. The microwave heating path affected
the macropores and microcracks and the crack development mode. When
the same microwave energy was applied, microwave heating on the coal
was mainly manifested by the opening of closed pores, before the pyrolysis
temperature of the coal was reached. Increasing the energy density
caused the water vapor to move from constant pressure expansion to
constant volume expansion. This resulted in an exponential growth
of the mesopore and macropore volumes. Meanwhile, the micropore volume
increased due to the collapse of pore structures. As a result, high-power
microwave heating could accelerate the vaporization rate of water.
The rapid expansion of water vapor volume brought about a microwave
heating effect similar to the “steam explosion”. The
resulting local tensile stress enabled the cracks to develop, expand,
and connect to others continuously. Thus, it formed a complex crack
network leading to the outside of the coal sample.