Metal Organic Framework Derived Materials: Progress and Prospects for the Energy Conversion and Storage

Indra, Arindam; Song, Taeseup; Paik, Ungyu

doi:10.1002/adma.201705146

Cited by 432 publications

(247 citation statements)

References 325 publications

(321 reference statements)

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“…In sharp contrast to the inorganic electrode materials, their diverse topology structure, tunable porosity, and abundant metal ions allow them to be a promising energy storage material . However, the poor conductivity and lack of structural stability of pristine MOFs remain the critical limitations for practical applications in energy storage devices . Except for MOFs‐derived nanocarbons or metal compounds, hybridizing MOFs with conductive polymers or carbon substrates is an additional productive tactic to improve the conductivity and stability, which can accelerate the electron transfer and reduce the inner resistance during the electrochemical reactions, even though the loading of active MOF species is lowered by the existence of conducting materials in a hybrid composition .…”

mentioning

confidence: 99%

Redox Tuning in Crystalline and Electronic Structure of Bimetal–Organic Frameworks Derived Cobalt/Nickel Boride/Sulfide for Boosted Faradaic Capacitance

et al. 2019

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The development of efficient electrode materials is a cutting‐edge approach for high‐performance energy storage devices. Herein, an effective chemical redox approach is reported for tuning the crystalline and electronic structures of bimetallic cobalt/nickel–organic frameworks (Co‐Ni MOFs) to boost faradaic redox reaction for high energy density. The as‐obtained cobalt/nickel boride/sulfide exhibits a high specific capacitance (1281 F g−1 at 1 A g−1), remarkable rate performance (802.9 F g−1 at 20 A g−1), and outstanding cycling stability (92.1% retention after 10 000 cycles). An energy storage device fabricated with a cobalt/nickel boride/sulfide electrode exhibits a high energy density of 50.0 Wh kg−1 at a power density of 857.7 W kg−1, and capacity retention of 87.7% (up to 5000 cycles at 12 A g−1). Such an effective redox approach realizes the systematic electronic tuning that activates the fast faradaic reactions of the metal species in cobalt/nickel boride/sulfide which may shed substantial light on inspiring MOFs and their derivatives for energy storage devices.

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mentioning

confidence: 99%

Redox Tuning in Crystalline and Electronic Structure of Bimetal–Organic Frameworks Derived Cobalt/Nickel Boride/Sulfide for Boosted Faradaic Capacitance

et al. 2019

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“…From the discovery of the MOF, more than 82,000 MOFs have been reported in last three decades with different applications . These highly porous materials have been employed for the absorption of greenhouse gases, sensors, catalysis and energy storage . The ultra‐high porosity, large inner surface area, tailored morphology and required composition of the MOF is beneficial to attain the required properties.…”

Section: Energy Conversion and Storagementioning

confidence: 99%

“…Room temperature crystallization, hydrothermal, microwave, sonochemical and even solid state synthesis have been employed for the preparation of the MOF . Core‐shell structured MOF have been reported while introducing a second metal in the structure.…”

Section: Energy Conversion and Storagementioning

confidence: 99%

“…Control over the composition with mixed metal systems and replacement of the metal centers with a second metal has also been achieved . The morphological development includes the formation of hollow sphere, hollow polyhedron, yolk‐shell structure providing a wide option for the material science . Direct use of the MOF for the electrochemical processes has been studied by various groups .…”

Section: Energy Conversion and Storagementioning

confidence: 99%

“…A series of transition metal‐based materials has been explored in the last decade to obtain higher activity and long‐term stability . In this context, metal organic framework (MOF) derived materials have received enormous attention due to their structural and morphological features, large surface area, controlled composition and tailored properties …”

Section: Introductionmentioning

confidence: 99%

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Electrochemical Energy Conversion and Storage with Zeolitic Imidazolate Framework Derived Materials: A Perspective

et al. 2018

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The development of transition‐metal‐based materials for electrochemical energy conversion and storage has received immense interest throughout the last two decades. In this respect, zeolitic imidazolate framework (ZIF)‐derived materials are particularly important for accessing various morphologies, sizes, exposed facets, variations in the electronic structure, high surface area, and large numbers of available active sites. The properties of the ZIF‐derived materials can be tuned by applying different synthetic protocols, introducing a heteroatom in the ZIF structure or by accessing core‐shell or hollow structures. Many studies have described the beneficial effects of ZIF‐derived materials, but no critical review is available in the growing field of electrochemical energy conversion and storage. Herein, we have described the basic principles of material synthesis from ZIFs, their applications in electrochemical processes, difficulties with the synthesis, and their future development.

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Metal–Organic Framework (MOF) Derived Electrodes with Robust and Fast Lithium Storage for Li‐Ion Hybrid Capacitors

Dubal

Jayaramulu

Sunil

et al. 2019

Adv Funct Materials

157

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Hybrid metal-organic frameworks (MOFs) demonstrate great promise as ideal electrode materials for energy-related applications. Herein, a wellorganized interleaved composite of graphene-like nanosheets embedded with MnO 2 nanoparticles (MnO 2 @C-NS) using a manganese-based MOF and employed as a promising anode material for Li-ion hybrid capacitor (LIHC) is engineered. This unique hybrid architecture shows intriguing electrochemical properties including high reversible specific capacity 1054 mAh g −1 (close to the theoretical capacity of MnO 2 , 1232 mAh g −1 ) at 0.1 A g −1 with remarkable rate capability and cyclic stability (90% over 1000 cycles). Such a remarkable performance may be assigned to the hierarchical porous ultrathin carbon nanosheets and tightly attached MnO 2 nanoparticles, which provide structural stability and low contact resistance during repetitive lithiation/delithiation processes. Moreover, a novel LIHC is assembled using a MnO 2 @C-NS anode and MOF derived ultrathin nanoporous carbon nanosheets (derived from other potassium-based MOFs) cathode materials. The LIHC full-cell delivers an ultrahigh specific energy of 166 Wh kg −1 at 550 W kg −1 and maintained to 49.2 Wh kg −1 even at high specific power of 3.5 kW kg −1 as well as long cycling stability (91% over 5000 cycles). This work opens new opportunities for designing advanced MOF derived electrodes for next-generation energy storage devices.and power density as well as long cycle life at low cost. [1][2][3][4] In this context, a new system called "lithium-ion capacitors (LICs)" is proposed in the beginning of 21st century, which is hybrid arrangement of a battery-like (as anode) and supercapacitor-like electrodes (as cathode) in organic electrolyte, heading to enhance energy and power densities. [5][6][7] It has been emphasized that LIC bridges the low energy density supercapacitors (SCs) and low power Li-ion batteries (LIBs). [8,9] Such an excellent performance of LIC in terms of energy and power density is assigned to the coupling effect from the rapid charging rate of capacitor-type electrode, the large specific capacity of the battery-like electrode, and the much wider working potential window of the organic electrolytes. [5,6] So far, several hybrid LIC designs have been realized, which are based on an activated carbon (AC) cathode combined with graphite, Li 4 Ti 5 O 12 (LTO), vanadates (Li 3 VO 4 , BiVO 4 , etc.), or metal oxides anodes. [10][11][12][13][14][15][16] However, the poor rate capability of graphite, the relatively high redox potential (≈1.5 V, vs Li/Li + ) of LTO, the poor electrical conductivity, and the cycle stability of metal oxides hamper their utilization in high performance LICs. Therefore, it is crucial to explore the novel anode and cathode materials with high rate capability, good cycle stability, and low redox potential to achieve further improvements for hybrid LICs.

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Metal Organic Framework Derived Materials: Progress and Prospects for the Energy Conversion and Storage

Cited by 432 publications

References 325 publications

Redox Tuning in Crystalline and Electronic Structure of Bimetal–Organic Frameworks Derived Cobalt/Nickel Boride/Sulfide for Boosted Faradaic Capacitance

Redox Tuning in Crystalline and Electronic Structure of Bimetal–Organic Frameworks Derived Cobalt/Nickel Boride/Sulfide for Boosted Faradaic Capacitance

Electrochemical Energy Conversion and Storage with Zeolitic Imidazolate Framework Derived Materials: A Perspective

Metal–Organic Framework (MOF) Derived Electrodes with Robust and Fast Lithium Storage for Li‐Ion Hybrid Capacitors

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