Conductive-bridging random access memory (CBRAM) using
a cobalt
(Co) electrode has recently featured a CMOS-compatible process, excellent
data retention, and a sub-μA operating current level, which
are difficult to achieve by conventional CBRAM. However, the resistive
switching (RS) mechanism of Co CBRAM has not been extensively explored
compared to that of the conventional CBRAM cells using Ag, Cu, or
Ni as active metal electrodes. Because only implicit inferences based
on electrical measurements have been made, the formation of Co filaments
is not yet clearly understood. This study presents evidence of Co
filament formation in Co/10 nm SiO
x
/TiN
resistive random access memory (RRAM) using direct transmission electron
microscopy (TEM) observations. Co protrusions larger than 5 nm are
observed, and their exact atomic composition is investigated by spectroscopy.
We explain the RS operation of Co/SiO
x
/TiN cells based on the Co electromigration-mediated filament development
process through Co electrode deformation, protrusion, and subsequent
Co conductive bridge formation. An asymmetric RS operation and negative
temperature correlation of the resistance are found in low resistance
state (LRS) cells, which further supports the Co-involved RS operation
in Co/SiO
x
/TiN devices.