Metals intercalated in graphite. IV. Intercalation from CCl₄ solution and extraction of intercalated species

Abstract

. Can. J. Chem. 54, 2505Chem. 54, (1976.Some chlorides, mainly of transition elements, can be intercalated in graphite from a solution of carbon tetrachloride if their solubility is in the range of 1 to 4 mg/ml in CCL, at reflux temperature, in the presence of chlorine.The rate of extraction of intercalated salts with solvents has been compared to the rate of solution of these salts in the same solvents.JEAN MARC LALANCETTE, LINDA ROY et JEANNINE LAFONTAINE. Can. J. Chem. 54, 2505 (1976).Certains chlorures derives principalement des metaux de transition ont pu &tre inserts dans le graphite, en presence du chlore et a la temperature de reflux, a partir de leurs solutions dans le tetrachlorure de carbone lorsque leurs solubilites se situaient dans la region 1 a 4 mg/ml de CCI,.La vitesse &extraction des sels inserks par certains solvants a 6te comparte a la vitesse de dissolution de ces sels dans les m&mes solvants.

Superacid‐Catalyzed Reactions

“…Lalancette et al 188 indicated that intercalation process can be carried out in CCl 4 solution only if the Lewis acid halide is slightly soluble in the solvent. Lalancette et al 188 indicated that intercalation process can be carried out in CCl 4 solution only if the Lewis acid halide is slightly soluble in the solvent.…”