“…Reports of crystalline flavonoids in plants are more infrequent. Of the wide variety of flavonoids, hesperidin and diosmin crystals were observed in rock samphire ( Crithmum maritimum ), Citrus limon and Barosma betulina (Cornara et al ., ) and quercetin crystals were found in Astrophytum (Iwashina et al ., ). Investigations of these flavonoid crystals were performed by elemental analysis using energy dispersive X‐ray spectroscopy, component analysis of the extracts using high performance liquid chromatography (HPLC) (Cornara et al ., ) and UV spectral analysis (Iwashina et al ., ), nevertheless the in situ detection and identification of flavonoid crystals have not yet been accomplished.…”