“…Microplasma science and technology is an intersection of plasma science, photonics, and materials science, which offers not only a realm of plasma phenomenology but also device functionality [ 1 - 4 ]. Such plasma-based devices exhibit great potential for a broad spectrum of applications in microdisplays, on-chip frequency standards, materials synthesis, elemental analysis, and detectors of environmentally hazardous or toxic gases or vapors [ 5 - 11 ] But due to the insufficient luminous efficiency of the plasma devices [ 12 ], development of a cathode material with efficient emission of secondary electrons for improving the initiation efficiency of plasma illumination is thus called for. Among carbon-based materials, diamond is a promising material for applications in various electronic and microelectromechanical devices due to its unparalleled intrinsic properties such as wide energy band gap, chemical inertness, extreme hardness, high thermal conductivity, and negative electron affinity [ 13 - 16 ].…”