Filler-free (FF) welding processes namely, Activated Tungsten Inert Gas welding (ATIG), Laser Beam Welding (LBW), and Friction Stir Welding (FSW) were utilized for joining the nuclear grade 9Cr-1Mo-V-Nb ferritic-martensitic steel and 316 L(N) austenitic stainless steel. A comparative investigation was made by assessing the weld geometries, metallurgical features, material mixing proportions, carbon diffusion behaviour, and mechanical properties of the post-weld heat-treated (PWHT) dissimilar weld joints. Geometries of the weld zones were observed with the transverse and longitudinal macrographs. Metallurgical features were examined by optical microscopy (OM) and Scanning electron microscopy (SEM). Three-phase microstructures were identified in the dissimilar weld zones (DWZ). The elemental distributions were identified by Energy-dispersive X-ray spectroscopy (EDAX). The mixing proportions of the dissimilar alloys and the formation of δ-ferrite in the dissimilar heat-affected zones (HAZ) and DWZ were analytically quantified. Moreover, the diffusion activity of carbides/interstitial carbon atoms was examined by Secondary ion mass spectroscopy (SIMS). In the FSW joints, the intermingled microstructures are recorded with high and stabilized hardness values as compared to the DWZ of the ATIG and LBW joints. In the transverse tensile test, all FF joints were failed at the 316 L(N) base metal (BM) region. Tensile and impact testing of all weld metal indicated that, the weld metal region of the LBW joint exhibited higher strength and lower toughness as compared to the ATIG and FSW joints. The presence of untransformed, recrystallized fine equiaxed austenite along and refined martensitic structure arranged in an alternate layers within the weld metal region of FSW joint caused the higher toughness property than the ATIG and LBW joints.