Molecular Iodine: Recent Application in Heterocyclic Synthesis

Veisi, Hojat

doi:10.2174/138527211796150570

Cited by 59 publications

(13 citation statements)

References 116 publications

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“…Prolonging the reaction time and increasing the iodine concentration did not improve appreciably the yields. Recently, Veisi [19] and Mphahlele [20] surveyed the applications of molecular iodine to the synthesis of a number of heterocyclic compounds that can be viewed as monomers for ROP.…”

Section: Monomers' Synthesismentioning

confidence: 99%

Molecular iodine in monomer and polymer designing

Moulay

2013

Designed Monomers and Polymers

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Not only does the molecular iodine play a leading role in organic synthesis but also in the polymer synthesis. Different kinds of polymerization initiated by molecular iodine are herein screened: cationic polymerization, radical polymerization, living/controlled radical polymerization (LCRP) such as reverse iodine transfer polymerization, polycondensation, and ring-opening polymerization (ROP). Also, the functionalization of polymers using molecular iodine, such as the acetylation of polysaccharides (cellulose, starch), and the use of iodine-polymer complex in organic synthesis are also discussed. Numerous natural and synthetic polymers are prone to make complexes with molecular iodine, and one feature of such complexes is their propensity as polymer-supported reagent and catalysts in many organic syntheses.

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Section: Monomers' Synthesismentioning

confidence: 99%

Molecular iodine in monomer and polymer designing

Moulay

2013

Designed Monomers and Polymers

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“…[1,2] The α-halogenated carbonyl compounds are valuable intermediate in synthetic organic chemistry [3]. These compounds are useful synthetic intermediates for various transformations and employed in the synthesis of biological active substrates such as antiviral, antifungal, antineoplastic, antibacterial, antitumor compounds [4].…”

Section: Introductionmentioning

confidence: 99%

Side Chain Chlorination of 4- Methoxy Toluene by an Electro Chemical Method

Varma¹,

Ganesan²,

Muruganandam³

2018

IJERMT

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Abstract:simple method for the preparation of 4-Methoxy Benzylchloride from 4-Methoxy Toluene is reported. The electrolysis was carried out at room temperature in a divided electrochemical cell fitted with graphite electrodes. The conversion of 4-Methoxy Toluene varies from 80 to 85 % and the selectivity observed is above as 99%. The effects of different electrode, solvent, current densities are studied and reported.

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“…Molecular iodine has several advantages as it is inexpensive, readily available, less toxic than alternatives, and a moisture-stable catalyst for organic transformations. Many organic reactions using molecular iodine as catalyst are often associated with mild conditions, short reaction times and simple work-up procedures [47][48][49][50][51][52][53].…”

Section: Introductionmentioning

confidence: 99%