1996
DOI: 10.3139/217.960373
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Molecular Orientation in Polycarbonate Induced by Cooling Stresses

Abstract: The origin of the maximum of the birefringence at the surface of injection-molded polymer products is discussed. By systematic variation of the molding conditions with polycarbonate, it is shown that the maximum at the surface not only depends on the filling, but even more so on the packing conditions. The birefringence at the surface is equal in the flow direction and transverse to it. The height scales with the cavity pressure during compression and packing. This cannot be explained by stresses due to the cl… Show more

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Cited by 13 publications
(7 citation statements)
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“…Kim [5], Despa et al [6], and Wimberger-Friedl [7] found that the mold temperature must be above the softening temperature to mold microchannels with a high-aspect ratio. Kim [5] also found that the filling percentages in microchannels are less than 10% if the mold temperature is less than 90°C for HDPE, whose melting temperature is 125°C.…”
Section: Effects Of Injection Speed Mold Temperature and Materialsmentioning
confidence: 99%
See 2 more Smart Citations
“…Kim [5], Despa et al [6], and Wimberger-Friedl [7] found that the mold temperature must be above the softening temperature to mold microchannels with a high-aspect ratio. Kim [5] also found that the filling percentages in microchannels are less than 10% if the mold temperature is less than 90°C for HDPE, whose melting temperature is 125°C.…”
Section: Effects Of Injection Speed Mold Temperature and Materialsmentioning
confidence: 99%
“…for x* Յ 0.001 7.541 ϩ 6.874͑1000x*͒ Ϫ0.488 e Ϫ245x* for x* Ͼ 0.001 (7) where x* is the dimensionless axial distance from the entrance, which is defined as:…”
Section: Numerical Analysismentioning
confidence: 99%
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“…Several authors have reported that increasing mold temperature and injection velocity improves the replication of microfeatures [6][7][8][9][10][11][12][13][14]. However, only limited quantitative data exists on how the mold temperature and the injection velocity influence replication.…”
Section: Introductionmentioning
confidence: 99%
“…Because of the different thermomechanical history the melt undergoes, the injection-molded parts often show a hierarchical multilayered structure through the thickness [1][2][3][4][5][6][7][8][9]. For the universal semicrystalline polymer, Polypropylene (PP), this layered structure has been widely studied with its heterogeneous crystallization because of the shear and temperature gradient [10][11][12][13][14][15][16][17][18][19].…”
Section: Introductionmentioning
confidence: 99%