Molecularly imprinted ormosil as a sorbent for targeted dispersive solid phase micro extraction of pyriproxyfen from strawberry samples

Hayat, Muhammad Khizar; Manzoor, Suryyia; Raza, Hina; Khan, Muhammad Imran; Shanableh, Abdallah; Sajid, Muhammad; Almutairi, Tahani Mazyad; Molina-Luque, Rafael

doi:10.1016/j.chemosphere.2023.137835

Cited by 12 publications

(4 citation statements)

References 38 publications

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“…With the help of kinetic models, the expected mechanism and the adsorption pathway being followed can be predicted . Adsorption process is expected to follow a variety of mechanisms, based on which it can be deduced if the adsorption process is physical or chemical in nature.…”

Section: Resultsmentioning

confidence: 99%

“…Adsorption process is expected to follow a variety of mechanisms, based on which it can be deduced if the adsorption process is physical or chemical in nature. Generally, the pseudo-first-order model describes diffusion-based adsorption, while the second-order model is more specifically followed in case of chemical adsorption, which involves the exchange of electrons between the membrane and adsorbate. , For EB adsorption onto the developed porous AEM from wastewater, adsorption kinetics were illustrated by applying several kinetics models. The graphs of the kinetic models used are shown in Figure , and Table contains calculated kinetic factors.…”

Section: Resultsmentioning

confidence: 99%

“…With the help of kinetic models, the expected mechanism and the adsorption pathway being followed can be predicted. 73 Adsorption process is expected to follow a variety of mechanisms, based on which it can be deduced if the adsorption process is physical or chemical in nature. Generally, the pseudo-first-order model describes diffusion-based adsorption, while the second-order model is more specifically followed in case of chemical adsorption, which involves the exchange of electrons between the membrane and adsorbate.…”

Section: Resultsmentioning

confidence: 99%

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Adsorption of Eosin B from Wastewater onto the Prepared Porous Anion Exchange Membrane

Khan,

Elboughdiri,

Shanableh

et al. 2024

ACS Omega

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This research describes the fabrication of the porous trimethylamine (TMA)-grafted anion exchange membrane (AEM) over a phase inversion process. The synthesis of the generated AEM was verified using Fourier transform infrared (FTIR) spectroscopy. The fabricated porous AEM showed 240% water uptake (W R ), 1.45 mg/g ion exchange capacity (IEC), and a 9.0% linear expansion ratio (LER) at 25 °C. It exhibited a porous structure and higher thermal stability. It was utilized to remove eosin B (EB) from wastewater via the process of adsorption. The adsorption capacity of EB increased with time and the starting concentration of EB while decreasing with temperature and the AEM dosage. Adsorption isotherm investigation results showed that EB adsorption onto the porous AEM followed the Langmuir isotherm because the value of correlation coefficient (R 2 = 0.992) was close to unity. Because the correlation coefficient was close to one, it was determined through adsorption kinetic experiments that the adsorption of EB on the produced porous AEM was suitable for a pseudosecond-order model. Thermodynamic study about process of EB adsorption on the porous AEM revealed that there was an exothermic (ΔH°= −16.60 kJ/mol) and spontaneous process.

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

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Adsorption of Eosin B from Wastewater onto the Prepared Porous Anion Exchange Membrane

Khan,

Elboughdiri,

Shanableh

et al. 2024

ACS Omega

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“…Another category of organic substances that elicit detrimental impacts on aquatic organisms is pesticides, which are utilized to mitigate the damage caused by pests, insects, and undesirable vegetation to agricultural products. , Glyphosate (Gly) is a herbicide belonging to the organophosphate group . It is a white crystalline solid and is recognized as the most extensively utilized pesticide globally for weed control, particularly targeting broad-leaf weeds .…”

Section: Introductionmentioning

confidence: 99%

Tailoring Vanadium-Based Magnetic Catalyst by In Situ Encapsulation of Tungsten Disulfide and Applications in Abatement of Multiple Pollutants

Manzoor,

Aziz,

Raza

et al. 2023

ACS Omega

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A magnetic nanocomposite of tungsten and vanadium was employed as a catalyst for the mitigation of water contaminants, including a carcinogenic dye (Congo red, CR), a widely used pesticide (glyphosate), and the bacterial strain Escherichia coli . Additionally, it was subjected to several characterization techniques. X-ray diffraction spectroscopy examination validated the synthesized nanoparticles’ crystalline nature, and scanning electron microscopy and energy-dispersive X-ray analysis were employed to examine the morphology and elemental composition of the catalyst. The use of thermogravimetric analysis enabled the elaboration of the thermal behavior of tungsten sulfide–vanadium decorated with Fe 2 O 3 nanoparticles. The experiments were conducted under visible light conditions. The highest levels of photodegradation of 96.24 ± 2.5% for CR and 98 ± 1.8% for glyphosate were observed following a 180 min exposure to visible light at pH values of 6 and 8, respectively. The quantum yields for CR and Gly were calculated to be 9.2 × 10 –3 and 4.9 × 10 –4 molecules photon –1 , respectively. The findings from the scavenger analysis suggest the involvement of hydroxyl radicals in the degradation mechanism. The study evaluated the inhibition of E. coli growth when exposed to a concentration of 0.1 g/10 mL of the photocatalyst, utilizing a 1 mL sample of the bacterial strain. The successful elimination of CR and glyphosate from water-based solutions, along with the subsequent antibacterial experiments, has substantiated the efficacy of the photocatalyst in the field of environmental remediation.

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Highly effective and selective recovery of Gd(III) from wastewater by defective MOFs-based ion-imprinted polymer: Performance and mechanism

yang,

Zhou,

Zhang

et al. 2023

Chemical Engineering Journal

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Molecularly imprinted ormosil as a sorbent for targeted dispersive solid phase micro extraction of pyriproxyfen from strawberry samples

Cited by 12 publications

References 38 publications

Adsorption of Eosin B from Wastewater onto the Prepared Porous Anion Exchange Membrane

Adsorption of Eosin B from Wastewater onto the Prepared Porous Anion Exchange Membrane

Tailoring Vanadium-Based Magnetic Catalyst by In Situ Encapsulation of Tungsten Disulfide and Applications in Abatement of Multiple Pollutants

Highly effective and selective recovery of Gd(III) from wastewater by defective MOFs-based ion-imprinted polymer: Performance and mechanism

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