In searching for solutions to reduce battery weight for military applications, films of hexanoyl chitosan/polystyrene containing ) and titanium oxide were prepared using filler were used, which are untreated TiO 2 and on the structural and electrical behavior of the prepared electrolyte systems has been investigated by using X-ray and impedance spectroscopy, respectively. The ac conductivity was calculated rmula in the temperature range from 283 K to 353 K. The SO 3 -TiO 2 and can be interpreted based on the correlated hexanoyl chitosan; polystyrene; composite polymer electrolytes.