Recent
advances in guiding and localizing light at the nanoscale exposed
the enormous potential of ultrascaled plasmonic devices. In this context,
the decay of surface plasmons to hot carriers triggers a variety of
applications in boosting the efficiency of energy-harvesting, photocatalysis,
and photodetection. However, a detailed understanding of plasmonic
hot carrier generation and, particularly, the transfer at metal–semiconductor
interfaces is still elusive. In this paper, we introduce a monolithic
metal–semiconductor (Al–Ge) heterostructure device,
providing a platform to examine surface plasmon decay and hot electron
transfer at an atomically sharp Schottky nanojunction. The gated metal–semiconductor
heterojunction device features electrostatic control of the Schottky
barrier height at the Al–Ge interface, enabling hot electron
filtering. The ability of momentum matching and to control the energy
distribution of plasmon-driven hot electron injection is demonstrated
by controlling the interband electron transfer in Ge, leading to negative
differential resistance.