The massively parallel arrays of highly periodic Gd-doped Si nanowires (SiNWs) self-organized on Si(110)-16 Â 2 surface were investigated by scanning tunneling microscopy and spectroscopy. These periodic Gd-doped SiNWs are atomically precise and show equal size, periodic positions, and high-integration densities. Surprisingly, the scanning tunneling spectroscopy results show that each metallic-like, Gd-doped SiNW exhibits room-temperature negative differential resistance (RT-NDR) behavior, which can be reproducible with various Gd dopings and is independent of the tips. Such massively parallel arrays of highly ordered and atomically identical Gd-doped SiNWs with one-dimensional laterally confined RT-NDR can be exploited in Si-based RT-NDR nanodevices. Negative differential resistance (NDR) is an important nonlinear electron transport property and is essential for device applications in current rectification, fast switching, logic circuits, high-frequency oscillators, and low-power memory circuits. [1][2][3] Motivated by the urge for electronic device miniaturization, NDR has been detected in tunneling conductance measurements for various low-dimensional systems, such as carbon nanotubes (CNTs), 4,5 semiconductor nanowires (NWs), 6-8 doped semiconductor surfaces, 9-11 and organic molecules, 12,13 by using scanning tunneling microscopy and spectroscopy (STM/STS). Several mechanisms have been proposed to explain the observed NDR. 4-13 From a technological perspective, the achievement of NDR nanoelectronics based on one-dimensional (1D) nanomaterials can efficiently be implemented in logic and memory nanocircuits. 14,15 Therefore, CNTs and NWs are promising 1D nanomaterials as active components in NDR nanoelectronic devices. However, NDR nanodevices based on a single NT or NW are not suitable for semiconductor manufacturing purposes, as it is difficult to control the electronic properties, growth, and alignment of individual NTs or NWs on an industrially reliable scale. For practical device applications, it is necessary to fabricate a large-area and well-ordered parallel array of periodically spaced and identical-size NTs/NWs for waferscale integration into an active parallel nanoarchitecture in real-world devices. 16 Recently, we have shown that the long-range, periodic upper Si terraces of 16 Â 2 reconstruction on a Si(110) surface can be recognized as massively parallel silicon NWs (SiNWs) grown naturally on a Si(110) surface. 17 SiNWs have been widely used as the basic building blocks of several nanodevices (e.g., field-effect transistors, logic gates, and biochemical sensors), 18-20 and they can be directly integrated into Si-based chips by means of Si-compatible nanofabrication technology. Moreover, transition-metal doped SiNWs have been shown to exhibit room-temperature (RT) ferromagnetism or halfmetallic ground state. [21][22][23] Because doped zigzag nanoribbons have been predicted to possess the NDR effect and magnetic properties simultaneously using the density-functional theory, 24,25 it is highly desira...