The aims of this study are to propose the linguistic picture fuzzy Dombi (LPFD) aggregation operators and decision-making approach to deal with uncertainties in the form of linguistic picture fuzzy sets. LPFD operators have more flexibility due to the general fuzzy set. Utilizing the Dombi operational rule, the series of Dombi aggregation operators were proposed, namely linguistic picture fuzzy Dombi arithmetic/geometric, ordered arithmetic/ordered geometric and Hybrid arithmetic/Hybrid geometric aggregation operators. The distinguished feature of these proposed operators is studied. At that point, we have used these Dombi operators to design a model to deal with multiple attribute decision-making (MADM) issues under linguistic picture fuzzy information. Finally, an illustrative example to evaluate the emerging technology enterprises is provided to demonstrate the effectiveness of the proposed approach, together with a sensitivity analysis and comparison analysis, proving that its results are feasible and credible.