A numerical model is constructed to calculate the number densities of some excited species of nitrogen in low-pressure discharge nitrogen plasma, together with simultaneous solution of the self-consistent electron energy distribution function and N 2 -vibration distribution function. We consider species N 2 (X), N 2 (A), N 2 (B), N 2 (C), N 2 (a), N 2 (a ), N + 2 , N + 4 , N( 4 S) and e − . In addition to electron collisional reactions, diffusion losses and molecular relations are included. It is found that the ratio of number densities of N 2 (B) and N 2 (C) states can be a good measure of the electron kinetic temperature. The N 2 (C) state is found to be almost in a corona equilibrium, whereas the N 2 (B) state becomes mainly populated by N 2 (X, v ≥ 6) + N 2 (A) reaction and depopulated by collisional relaxation by the ground-state N 2 (X) molecule.