Noncentrosymmetric Ba6In2Q10 (Q = S, Se): Structural Chemistry and Nonlinear-Optical Activity

Huang, Xiao; Yang, Song; Liu, Wenlong; Guo, Sheng‐Ping

doi:10.1021/acs.inorgchem.1c03171

Cited by 9 publications

(6 citation statements)

References 61 publications

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“…Two types of Ga atoms are 4fold-coordinated with S atoms to construct distorted GaS 4 tetrahedra. The lengths of the Ba−S, Hg−S, and Ga−S bonds are 3.0408(9)−3.6604(11), 2.3301(10)−2.3573(10), and 2.2032(10)−2.3304(10) Å, consistent with those in Ba 6 In 2 S 10 , 26 HgS, 14 and AAgGa 6 S 10 (A = K, Rb, Cs), 27 respectively. Considering the ionicity of the Ba 2+ cations, the dimensionality of BHGS is determined by the anionic part.…”

supporting

confidence: 66%

Ba₃HgGa₂S₇: A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg₂Ga₄S₁₄]^12– String and Exhibiting a High Photocurrent Response

et al. 2022

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The discovery of new types of metal sulfides is attractive because of their rich structures and diverse physical properties. Here, a novel quaternary sulfide, Ba3HgGa2S7 (BHGS), is obtained by a solid-state reaction at 1123 K. It crystallizes in the monoclinic space group P21/c, and its zero-dimensional structure features two seesaw-like HgS2 units and four GaS4 tetrahedra, constructing a unique [Hg2Ga4S14]12– string. BHGS has a wide band gap of 3.64 eV and a large birefringence of 0.09 at 2100 nm. Specifically, BHGS exhibits a remarkable photocurrent response. This work may be extended to a new family of AE3MIIMIII 2Q7 (AE = Mg, Ca, Sr, Ba; MII = Zn, Cd, Hg; MIII = Al, Ga, In; Q = S, Se) chalcogenides.

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supporting

confidence: 66%

Ba₃HgGa₂S₇: A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg₂Ga₄S₁₄]^12– String and Exhibiting a High Photocurrent Response

et al. 2022

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“…Five novel melilite‐type oxychalcogenide IR NLO materials with the formula of Sr 2 MN 2 OS 6 , that is, Sr 2 ZnSn 2 OS 6 , [24a] Sr 2 ZnGe 2 OS 6 , [27] Sr 2 CdGe 2 OS 6 , [27] Sr 2 MnGe 2 OS 6 [27] and Sr 2 CoGe 2 OS 6 , [28] were reported in 2022. Before these reports, the structures of Sr 2 ZnGe 2 OS 6 and Sr 2 MnGe 2 OS 6 were reported, [29] nevertheless, their NLO properties had not been studied by then.…”

Section: Materials Structures and Propertiesmentioning

confidence: 99%

Oxychalcogenides: A Promising Class of Materials for Nonlinear Optical Crystals with Mixed‐Anion Groups

Zhang

et al. 2023

Chemistry A European J

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Infrared nonlinear optical (IR NLO) materials are of great significance in the development of IR laser technology. But rationally designing high‐performance IR NLO materials remains a huge challenge due to the conflict between the necessary properties required for NLO materials. Notably, oxychalcogenides with mixed‐anion groups have drawn extensive interest as a family of important IR NLO candidates because they integrate the property advantages of oxides and chalcogenides by chemical substitution engineering. In this review, we provide a survey of reported oxychalcogenides and aim to present the development of NLO oxychalcogenides from the perspective of rational design of their structural chemistry. Furthermore, we focus on the relationships between partial substitution and structural symmetry as well as optical properties. These provide some helpful guidance for the further exploration and design of novel oxychalcogenide materials with excellent NLO performance in the future.

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“…Chemical substitution is a common strategy in the design of NLO crystals. [70][71][72][73][74][75] Single cations are more isotropic than polycations and tend to form a structural framework with higher symmetry. Compared with simple element substitution, anisotropic polycationic substitution can greatly improve the flexibility of crystal structure.…”

Section: [Aba 2 Cl][ga 4 S 8 ] (A = Rb Cs)mentioning

confidence: 99%

“…Chemical substitution is a common strategy in the design of NLO crystals [70–75] . Single cations are more isotropic than polycations and tend to form a structural framework with higher symmetry.…”

Section: Salt‐inclusion Chalcohalidesmentioning

confidence: 99%

Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials

Han

Guo

2022

Eur J Inorg Chem

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In the past few decades, many new infrared (IR) second-order nonlinear optical (NLO) materials have been prepared by various synthetic methods to satisfy the growing market demand. However, few ones have the high potentials to be applicable since their comprehensive NLO properties cannot meet the standards, which include a series of indicators like large NLO effects, high laser-induced damage thresholds (LIDTs), phase matchability, high thermal stability, good growth habit, and so on. Considering the available IR NLO materials' disadvantages and the market requirements, it is necessary to continuously explore new high-performance ones. Hitherto, lots of chalcogenides, halides, and oxides have been explored as IR NLO materials. Recently, researchers have found that the combination of two or more structural units into one structure may achieve good NLO properties, as evidenced by the fact that diverse materials with multiple anions are receiving growing interest. Specifically, chalcohalides are highly promising as they may combine the advantages of chalcogenides and halides, viz. large NLO coefficients and wide IR transparency of the former, and large band gaps and high LIDTs of the latter. To address the status of chalcohalides, this review focuses on the newest progresses on this topic (mainly from the last five years), including ternary chalcohalides, quaternary chalcohalides, saltinclusion chalcohalides, and rare-earth chalcohalides. Here we summarize and analyze their compositions, crystal structures, NLO properties, and discuss the structure-property relationship. Finally, the development prospects for NLO chalcohalides are given.

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Noncentrosymmetric Ba₆In₂Q₁₀ (Q = S, Se): Structural Chemistry and Nonlinear-Optical Activity

Cited by 9 publications

References 61 publications

Ba₃HgGa₂S₇: A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg₂Ga₄S₁₄]^12– String and Exhibiting a High Photocurrent Response

Ba₃HgGa₂S₇: A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg₂Ga₄S₁₄]^12– String and Exhibiting a High Photocurrent Response

Oxychalcogenides: A Promising Class of Materials for Nonlinear Optical Crystals with Mixed‐Anion Groups

Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials

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Noncentrosymmetric Ba6In2Q10 (Q = S, Se): Structural Chemistry and Nonlinear-Optical Activity

Cited by 9 publications

References 61 publications

Ba3HgGa2S7: A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg2Ga4S14]12– String and Exhibiting a High Photocurrent Response

Ba3HgGa2S7: A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg2Ga4S14]12– String and Exhibiting a High Photocurrent Response

Oxychalcogenides: A Promising Class of Materials for Nonlinear Optical Crystals with Mixed‐Anion Groups

Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials

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Noncentrosymmetric Ba₆In₂Q₁₀ (Q = S, Se): Structural Chemistry and Nonlinear-Optical Activity

Ba₃HgGa₂S₇: A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg₂Ga₄S₁₄]^12– String and Exhibiting a High Photocurrent Response

Ba₃HgGa₂S₇: A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg₂Ga₄S₁₄]^12– String and Exhibiting a High Photocurrent Response