European Union legislation requires organizations to assess their processes in the context of risk management. The main task of risk management is to manage all risks that can significantly affect the outcome of processes. The article is focused on risk evaluation in pressure leaching at elevated temperature using the method Fault Tree Analysis (FTA). The effectivity of pyrite and arsenic pyrite decomposition by oxidative pressure leaching is influenced by the duration of the process, by the temperature, concentration of the leaching solution and by a density of the slurry. It was found that, under equitable conditions, the arsenic pyrite decomposes more intensely than pyrite. Under laboratory conditions, leaching is performed in an autoclave. Due to the aggressive environment, increased pressure and temperature, process failure is possible. Its probability was calculated by FTA. It has been found that the probability of the top event in the examined process was disproportionately high (0.057) and represents an invitation to take corrective actions. The Monte Carlo method was used for the simulation of the effect the probability of basic events on the probability of the top event—the failure of the leaching process.