“…A combination of monomers that satisfies these requirements is styrene and p-hydroxystyrene. Poly(p-hydroxystyrene) (pHS) and its derivatives are of interest for, e.g., applications in photoresist materials, [34][35][36][37] removal of organic material from aqueous waste via adsorption, 38 and as light-emitting devices. 39,40 In order to effectively polymerize p-hydroxystyrene, the acidic proton needs to be protected.…”
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“…A combination of monomers that satisfies these requirements is styrene and p-hydroxystyrene. Poly(p-hydroxystyrene) (pHS) and its derivatives are of interest for, e.g., applications in photoresist materials, [34][35][36][37] removal of organic material from aqueous waste via adsorption, 38 and as light-emitting devices. 39,40 In order to effectively polymerize p-hydroxystyrene, the acidic proton needs to be protected.…”
Take-down policy If you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim.
“…Despite that deactivated aromatics do not react under the reaction conditions, this methodology of diaryl sulfoxides should provide a convenient route to the preparation of tri-arylsulfonium salts which are used as photoactive cationic initiators 7 and for the photogeneration of protonic acid in the lithographic resist field. 8,9…”
The preparation of symmetrical diaryl sulfoxides from thionyl chloride and arenes catalyzed by trifluoromethanesulfonic acid is described. The reaction is characterized by its mildness, high yields, selectivity, and ease of workup.
“…Despite that deactivated aromatics do not react under the reaction conditions, this methodology of diaryl sulfoxides should provide a convenient route to the preparation of triarylsulfonium salts which are used as photoactive cationic initiators 7 and for the photogeneration of protonic acid in the lithographic resist field. 8,9 …”
The preparation of symmetrical diaryl sulfoxides from thionyl chloride and arenes catalyzed by trifluoromethanesulfonic acid is described. The reaction is characterized by its mildness, high yields, selectivity, and ease of workup.
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