2015
DOI: 10.1002/adma.201502088
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Oligosaccharide Carbohydrate Dielectrics toward High‐Performance Non‐volatile Transistor Memory Devices

Abstract: Oligosaccharides are one of the most promising biomaterials because they are abundant, renewable, diversified, and biosourced. The use of oligo- or polysaccharides for high-performance non-volatile organic field-effect-transistor memory is demonstrated herein. The charge-storage mechanism is attributed to charged hydroxyl groups that induce stronger hydrogen bonding, thus leading to the stabilization of trapped charges. This study reveals a promising future for green memory devices.

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Cited by 65 publications
(55 citation statements)
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“…In addition, biomaterials allow a biocompatible interface between electronic devices and biological worlds, thus broadening corresponding biotechnological and medicinal applications, such as implantable chips, artificial neurons, and electronic skin 20, 21, 22, 23, 24. Various types of biomaterials have been used as active units for fabrication of data‐storage devices, such as protein, polysaccharide, nucleic acid, and virus 25, 26, 27, 28, 29, 30. Due to versatile properties, such as biodegradability, biocompatibility, bioresorbability, optical transparency, and light weight, proteins, the most readily accessible biomolecules can be used as an attractive building blocks for the development of RRAM devices and endow these electronic memories with excellent performance and environmental benignity 31, 32.…”
mentioning
confidence: 99%
“…In addition, biomaterials allow a biocompatible interface between electronic devices and biological worlds, thus broadening corresponding biotechnological and medicinal applications, such as implantable chips, artificial neurons, and electronic skin 20, 21, 22, 23, 24. Various types of biomaterials have been used as active units for fabrication of data‐storage devices, such as protein, polysaccharide, nucleic acid, and virus 25, 26, 27, 28, 29, 30. Due to versatile properties, such as biodegradability, biocompatibility, bioresorbability, optical transparency, and light weight, proteins, the most readily accessible biomolecules can be used as an attractive building blocks for the development of RRAM devices and endow these electronic memories with excellent performance and environmental benignity 31, 32.…”
mentioning
confidence: 99%
“…Ru II complexes have been extensively studied as electrochromic materials, [67][68][69][70] but there are few reports for them as ELC materials. ELC Ru II complexes were designedm ainly by the PeT mechanism or the mutual conversiono ft he different redox states of Ru II center.L ehn et al designed the luminescent Ru II complex Ru-1 ( Figure 6), which connected ar edox-activeq uinone moiety on one bipyridine ligand of photoactive Ru(bpy) 3 2 + core. [38] Complex Ru-1 displayed red emission, large Stokes shift and long lifetime.…”
Section: Electroluminochromism Based On Ru II Complexesmentioning
confidence: 99%
“…Stimulus-responsivem aterials have attracted considerable attention due to their enormous potentiala pplications in the fields of data storage, [1][2][3][4] sensors, [5,6] biomedicine [7,8] and information displays. [9][10][11][12] The applied external stimuli include temperature, [13,14] light, [15][16][17][18][19] mechanical force, [20][21][22][23][24][25][26][27] solvento r vapor, [28][29][30] and electric or magnetic fields, [31,32] etc.…”
Section: Introductionmentioning
confidence: 99%
“…The resultant hydroxylate anions potentially enhance hydrogen bonding to improve the electron charge storage in the polysaccharides. 79 In addition to the structure of the polysaccharide/semiconductor heterojunction, the interaction between the polysaccharide/ semiconductor was reduced using a maltoheptaose-b-polystyrene block copolymer (MH-b-PS) as the electret in a transistor memory device ( Figure 15). Notably, the memory behavior can be converted to flash-type memory because the PS block serves as a tunneling layer and the charge-storage density (that is, the memory window) corresponds to the self-assembly MH block embedded in the PS matrix.…”
Section: Gate Dielectric Layers In Organic Field-effect Transistorsmentioning
confidence: 99%