Two- and three-dimensional superlattices of passivated silver nanoparticles
were formed on amorphous carbon films by the self-assembly technique. The x-ray
diffraction (XRD) and x-ray photoelectron spectroscopy results
demonstrated that the colloid system was composed of silver nanoparticles
and, on the surface of the silver nanoparticles, the chemical bond was formed
between the S of the 1-nonanethiol and the Ag of the particle. XRD and
transmission electron microscopy also showed that the instability of
the silver nanoparticles mainly resulted from the growth of
the nanoparticles. Due to the relatively close-packed thiol layer on the
surface of the nanoparticle, in the infrared spectra of the silver nanoparticles,
absorption peaks of the terminal methyl group and methylene stretching modes
were red shifted; meanwhile the transverse modes of the binding absorption
disappeared.