“…Moreover, the spectral observations from ref 23 are inconsistent to other reports, and the originally anticipated quantum condition (E emission = hv = qV bias , 24 where v is the frequency, q the charge, V bias the applied voltage bias, and h Planck constant) is experimentally not validated. 19,23,25,26 This can be attributed to the fact that (a) increasing the electron energy distribution via hot carriers can change the quantum condition (e.g., hv > qV bias ), 26 which is a first order effect, and (b) the emission is governed by the overlap integral of the energy-dependent tunnel current with the modal dispersion. The argument of a convolution between the spectral-dependent tunnel current and the device-internal plasmon was made to explain the deviation from hv = qV bias , as further validated in results presented here.…”