“…Even though the quantum confinement effect can explain the PL photon energy in the visible spectral region and has been widely recognized, serious contradictions exist between its predictions and a number of experimental results. In addition, different surface chemical species have been suggested to be the light emitting center for the visible PL, such as siloxene, hydride species or polysilanes or hydrogenated amorphous silicon [1][2][3][4]. Each model has its advantage in some specific cases, but meets difficulties in other cases.…”