Organic‐Inorganic Hybrid Perovskite Nanomaterials: Synthesis and Application

Abstract

In recent years, organic‐inorganic hybrid perovskite materials have drawn immense attention in the application of optoelectronic devices due to their superior semiconductor characteristics. Among them, organic‐inorganic hybrid perovskite nanomaterials with advantages such as long charge carrier diffusion lengths, high charge carrier mobilities, low trap‐state‐density, high photoluminescence quantum efficiency and low‐cost solution processability have shown great development potential in the field of semiconductor devices. In this review, we firstly summarize several synthesis strategies for organic‐inorganic hybrid perovskite nanomaterials, including template method, hot injection method, ligand‐assistant reprecipitation strategy, chemical vapor deposition method, microfluidic reactor method, ultrasound synthesis and mechanical ball milling method and analyze their own advantages and limitations. Subsequently, the research progress in applications in the field of light emitting diodes, solar cells, lasers and photodetectors are reviewed. At the end of this review, current challenges and future developments are discussed.

Ambipolar Field‐Effect Transistor Based on CH3NH3PbI3 Microwires

“…In the past several years, organic‐inorganic hybrid perovskites with their salient carrier transport properties are recognized as promising solution‐processable semiconductors for the next‐generation solar cells, photodetectors and light‐emitting diodes [1–5] . Compared with the tremendous progress in practical application in these field, the situation is markedly different in some other electronic devices.…”

“…In the past several years, organic-inorganic hybrid perovskites with their salient carrier transport properties are recognized as promising solution-processable semiconductors for the nextgeneration solar cells, photodetectors and light-emitting diodes. [1][2][3][4][5] Compared with the tremendous progress in practical application in these field, the situation is markedly different in some other electronic devices. For example, field-effect transistors (FETs) are important electrical devices in modern electronics and also have been extensively used as a tool to characterize the charge carrier transport properties of materials.…”

Chemically modified nucleic acids and DNA intercalators as tools for nanoparticle assembly

“…[8][9][10][11][12][13] Recent advances in nanoparticle synthesis have made available a large library of nanoparticles of various morphologies. Metallic, metal oxide, semiconductor, magnetic, upconversion and perovskite nanoparticles have been developed in a variety of sizes and shapes, [14][15][16][17][18][19][20][21] and many of these can be prepared on a large scale. [22][23][24][25] The surface chemistry of these nanomaterials has been significantly explored and a versatile range of ligands have been reported to enable the stability of Ysobel Baker Ysobel R. Baker is a postdoctoral researcher in the Tom Brown Group.…”

EA-Directing Formamidinium-Based Perovskite Microwires with A-Site Doping

“… 9 − 14 There are several synthesis strategies for organic–inorganic hybrid perovskite nanomaterials, including the template method, hot injection method, ligand-assisted reprecipitation strategy, chemical vapor deposition method, microfluidic reactor method, ultrasound synthesis, and mechanical ball milling method. 15 − 19 In perovskite materials, the A-site cation, such as methylammonium (CH 3 NH 3 , MA), formamidinium (HC(NH 2 ) 2 , FA), or caesium (Cs), as an important effective component, plays a key role in tuning the crystal structure and optical and electronic properties. For example, Br vacancies and interstitials have much lower formation energies and higher density in MA cation-based perovskite than FA-based crystals, while a higher rotation barrier and stronger H-bonding between the organic cation and Br are in the latter case.…”

“…The great success of perovskite as a new generation of semiconducting materials has been widely witnessed in photovoltaics, light-emitting diodes (LEDs), transistors, photodetectors, and lasers. − With general chemical stoichiometry ABX 3 , perovskite is typically composed of cation A, metal cation B, and halide anion X. The wide feasibility of the combination of different cations and halide anions in perovskites has promoted large possibilities in compositional engineering for different applications. − There are several synthesis strategies for organic–inorganic hybrid perovskite nanomaterials, including the template method, hot injection method, ligand-assisted reprecipitation strategy, chemical vapor deposition method, microfluidic reactor method, ultrasound synthesis, and mechanical ball milling method. − In perovskite materials, the A-site cation, such as methylammonium (CH 3 NH 3 , MA), formamidinium (HC­(NH 2 ) 2 , FA), or caesium (Cs), as an important effective component, plays a key role in tuning the crystal structure and optical and electronic properties. For example, Br vacancies and interstitials have much lower formation energies and higher density in MA cation-based perovskite than FA-based crystals, while a higher rotation barrier and stronger H-bonding between the organic cation and Br are in the latter case .…”