“…Because of its unusually rich electronic properties, Bi has long been the subject of experimental and theoretical studies. [1][2][3][4][5][6][7][8][9][10][11] At high pressure, however, Bi is superconducting at low temperatures due to the formation of high-pressure metallic polymorphs, namely, monoclinic Bi-II at 2.55 GPa, 12,13 a complex tetragonal Bi-III at 2.7 GPa, 12,[14][15][16] and a bodycentered cubic (bcc) Bi-V at 7.7 GPa. 12,16,17 The transition temperatures of these polymorphic phases are respectively 3.9, 18,19 7.2, [18][19][20] and 8.3 K. 20,21 It was found that these highpressure phases could be preserved in a metastable state by subjecting the bulk crystal to compression cycles at room temperature and releasing the pressure at helium tempera-tures.…”