1993
DOI: 10.1016/0003-2670(93)85319-f
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pH and concentration response surfaces for the luminol—H2O2 electrogenerated chemiluminescence reaction

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Cited by 38 publications
(25 citation statements)
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“…Other investigators, however, have reported different pH maxima, which suggests that if the pH curve does reflect the ECL mechanism then the currently accepted mechanism of Haapakka and Kankare does not always apply. In particular a detailed study of the interrelationship between the concentrations of luminol and H 2 O 2 on ECL found that maximum light emission occurred in the range pH 9 to 10 [52]. In the present work maximum light emission at pH 8.0 was observed at a H 2 O 2 concentration of 10 mM; at higher H 2 O 2 concentrations light emission decreased (Fig.…”
Section: Effect Of Hydrogen Peroxide and Ph On Tmc And Luminol Eclsupporting
confidence: 50%
“…Other investigators, however, have reported different pH maxima, which suggests that if the pH curve does reflect the ECL mechanism then the currently accepted mechanism of Haapakka and Kankare does not always apply. In particular a detailed study of the interrelationship between the concentrations of luminol and H 2 O 2 on ECL found that maximum light emission occurred in the range pH 9 to 10 [52]. In the present work maximum light emission at pH 8.0 was observed at a H 2 O 2 concentration of 10 mM; at higher H 2 O 2 concentrations light emission decreased (Fig.…”
Section: Effect Of Hydrogen Peroxide and Ph On Tmc And Luminol Eclsupporting
confidence: 50%
“…They found that the electrode activity could be restored at a negative potential (16). To overcome the monotonic decrease, the effect of potential on the signal was investigated in the range from 0 to Ϫ0.4 V. The intensity and the stability of the CL signal increased with decreasing potential.…”
Section: Immobilization Methods and Stabilization Of Flow Injection Rementioning
confidence: 98%
“…The ECL of luminol can be also observed accompanied with certain co‐reactant, as hydrogen peroxide or other reactive oxygen species (ROSs, as O 2 •− , • OH, 1 O 2 etc.) by degrees of enhancement of its ECL intensity .…”
Section: Overview Of the Luminol Ecl Processmentioning
confidence: 99%