Phosphorazide und deren Schwingungsspektren

Abstract

Die Phosphorazide P(N3)3 (I), PO(N3)3 (II), und P(N3)5 (III) lassen sich durch Umsetzung der entsprechenden PCl‐Verbindungen und Natriumazid darstellen. III zerfällt in Lösung leicht in I und Stickstoff. Die Schwingungsspektren werden diskutiert. III ist kovalent aufgebaut und besitzt D3h‐Symmetrie.

Syntheses and structures of triazides of heavy group 15 elements

“…Neutral binary group 15 azides of the types E(N3)3 and E(N3)5 have been intensely studied over the last decades. While phosphorous triazide could be neither isolated nor structurally characterized and phosphorous pentaazide is still unknown, to date, [1] the corresponding complexes of the heavier group 15 15 elements, As(N3)3, [2] As(N3)5, [3] Sb(N3) 3[2b,4] and Sb(N3)5 [3] have been synthesized within the last few years. Moreover, thermally more stable ionic complexes containing anions of the types E(N3)4 -(E = As, Sb) [5] and E(N3)6 -(E = P, [6] As, [5,7] Sb [5,3]) as well as cations E(N3)4 + (E = P,[8] As, [5] Sb [5]) have 20 been synthesized and isolated.…”

Identification of a prismatic P3N3 molecule formed from electron irradiated phosphine-nitrogen ices

“…Overall, this work not only advances our fundamental perception of the chemical bonding of nitrogen and phosphorus systems, but also provides a potentially viable pathway to generate polyhedral compounds carrying pnictogens such as, for instance, the hitherto elusive hexa-nitrogen (N 6 ) molecules including D 6h planar hexaaza benzene 18 , 33 , C 2v hexaaza-Dewar benzene 33 , 34 , and D 3h hexaaza prismane 35 by extensive electron irradiation of pure nitrogen ice and distinguish them by selectively photoionizing the isomers with VUV photons. This approach may also be valuable for future studies of other binary P−N compounds similar to P 3 N 5 36 , P(N 3 ) 3 37 , P(N 3 ) 5 37 , and P 3 N 21 38 .…”

Electronic Structure of Binary Phosphoric and Arsenic Triazides

“…[8,9] For arsenic azides, much research has been devoted to the preparation and characterization of these compounds: [10] the first preparation of As(N 3 ) 3 and As(N 3 ) 4 + was reported by [10a,10c] the crystal structure of As(N 3 ) 3 was determined by ; [11] and the crystal structure of As(N 3 ) 6 -was determined by Klapötke et The electronic and molecular structures of many azides (unstable molecules) have been studied with theoretical and spectroscopic methods. [12] Recently, photoelectron spectroscopy in combination with high-level quantum chemical calculations has been successfully performed for elucidating many interesting aspects of monoazides [13] and diazides.…”