1995
DOI: 10.1021/ed072p842
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Photoelectroconversion by Semiconductors: A Physical Chemistry Experiment

Abstract: A physical chemistry experiment illustrating photochemistry, cyclic voltammetry, the properties of semiconductors, and surface chemistry is described. The experiment consists of constructing a liquid-junction photochemical cell, determining the cell parameters, then modifying the surface of the electrode to enhance the conversion efficiency of the cell. The students will learn some fundamental physical and chemical principles related to light and electricity interconversion as well as the properties of semicon… Show more

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Cited by 5 publications
(6 citation statements)
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“…This behavior can be graphically represented by the current-voltage (I-V ) curve of the cell at a given illumination and temperature, in which some working parameters that determine the efficiency of the cell, are displayed (Figure 1) (5). I-V curves are usually recorded applying a variable load and tracing the current (6). Measurements are carried out both under illumination 2 and under the dark.…”
Section: Characteristics Of Organic Solar Cellsmentioning
confidence: 99%
“…This behavior can be graphically represented by the current-voltage (I-V ) curve of the cell at a given illumination and temperature, in which some working parameters that determine the efficiency of the cell, are displayed (Figure 1) (5). I-V curves are usually recorded applying a variable load and tracing the current (6). Measurements are carried out both under illumination 2 and under the dark.…”
Section: Characteristics Of Organic Solar Cellsmentioning
confidence: 99%
“…However, despite multiple research articles describing these properties and the trends they follow as a function of the atomic number, learning through memorization can create misconceptions and confusion of basic chemical concepts that lead to low performance in science. , Therefore, some researchers have developed novel methodologies to understand the properties of elements and their periodicity through the use of didactic materials, 3D-printing technology, and discussion of fictional elements . As a complement, some articles discuss anomalous properties of elements that do not follow expected trends. , On the other hand, the teaching of solar cells often focuses on the concepts, fabrication, and characterization of solar cells without offering the chance to discuss or deeply analyze the impacts of the properties of materials in PV applications. Therefore, we have developed a homework activity in which students can evaluate energy levels of PV materials used in state-of-the-art perovskite (CH 3 NH 3 PbI 3 ) solar cells following the Mulliken electronegativity empiric procedure .…”
mentioning
confidence: 99%
“…Solar energy, an inexhaustible natural resource, is recognized as the most promising renewable energy source to meet the future energy demand and sustainable development of the planet . Photovoltaic (PV) cells, which convert solar energy to electricity, are becoming an increasingly popular form of alternative energy around the world. The fundamentals of PV cells and their pedagogical approach have been discussed in this Journal and elsewhere. , However, laboratory experiments to illustrate clearly the working of p–n junction-based solid-state PV cells are still needed.…”
mentioning
confidence: 99%