2021
DOI: 10.13005/ojc/370113
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Physical Properties of Films Based on Gelatin and Dialdehyde Starch with Different Oxidation Degrees

Abstract: In this study, dialdehyde starch (DAS) was prepared by oxidizing corn starch using potassium periodateas the oxidant.The aldehyde contentsin DAS weredetermined using titration with hydroxylamine and were found proportional to the molar ratio of KIO4:C6H10O5.Fourier transform infrared spectroscopy was used to confirm the breakage of the bond between C2 and C3in anhydroglucose units and the formation of -CHO group in DAS. X-ray diffractometry showed a decrease in crystallinity of starch after periodate oxidation… Show more

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Cited by 4 publications
(2 citation statements)
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“…Thermogravimetric curves for native corn starch, chitosan, and their dialdehyde derivatives are shown in Figure 8 . Although previous works showed changes in the thermal stability of oxidized starch and chitosan [ 39 , 40 , 46 , 47 , 48 ], specific thermal parameters have not been determined, and there is no detailed discussion and comparison with native biopolymers. TGA also provides information on the structure of the tested materials and may confirm the effectiveness of their oxidation process.…”
Section: Resultsmentioning
confidence: 99%
“…Thermogravimetric curves for native corn starch, chitosan, and their dialdehyde derivatives are shown in Figure 8 . Although previous works showed changes in the thermal stability of oxidized starch and chitosan [ 39 , 40 , 46 , 47 , 48 ], specific thermal parameters have not been determined, and there is no detailed discussion and comparison with native biopolymers. TGA also provides information on the structure of the tested materials and may confirm the effectiveness of their oxidation process.…”
Section: Resultsmentioning
confidence: 99%
“…The results for contact angle were significantly higher for collagen films cross-linked with DAS; thus, samples were characterized by lower hydrophilicity or a more hydrophobic character and lower wettability. Selected physicochemical properties of gelatin/DAS films were evaluated by Nguyet et al They also indicated that the higher the aldehyde content in films modified with DAS, the lower the hydrophilicity of the samples [46]. Bajer et al conducted contact angle measurements of native starch and dialdehyde starch blends, which resulted in confirmation of the hydrophobic influence of dialdehyde starch on studied materials [45].…”
Section: Contact Angle and Surface Energymentioning
confidence: 99%