Physical properties of pyridinium ionic liquids

(Vapour+liquid) equilibria, (VLE) excess molar enthalpies and infinite dilution activity coefficients of selected binary systems involving n-hexyl pyridinium bis(trifluoromethylsulphonyl)imide ionic liquid: Experimental and predictions using modified UNIFAC (Dortmund)

“…From figure 7, good agreement is observed between the experimental and literature values reported [22,23] except [21], which show a maximum deviation of ±0.00964 g Á cm À3 . It is also noticeable that there is a maximum deviation of ±0.0127 g Á cm À3 in reported literature values [26].…”

“…001 g Á cm À3 (0.95 level of confidence). together with literature (j) [21], (N) [22] and (d) [23] at different temperatures. …”

“…In the present study, limiting activity coefficients of ethanol, propan-1-ol, butan-1-ol, cyclohexane, benzene and toluene in [HPy][NTf 2 ] were also measured by the dilutor technique at four different temperatures in the range of (303.15 to 343.15) K. For accurate estimation of the vapour phase volume required in equation (1), the density of the ionic liquid was measured within the temperature range from (293.15 to 353.15) K. The newly obtained results are compared to previously published [21][22][23] values in table 6 and plotted in figure 7. From figure 7, good agreement is observed between the experimental and literature values reported [22,23] except [21], which show a maximum deviation of ±0.00964 g Á cm À3 .…”

New hydrophobic ionic liquids with perfluoroalkyl phosphate and cyanofluoroborate anions

“…Ionic liquids based on the FAP anion reveal an excellent electrochemical (Fig.3) [5,[7][8][9][10] and thermal stability [5,11,12]. They are less viscous than corresponding ionic liquids with the [PF 6 ] -anion [5,13,14].…”

Wettability and corrosion of [NTf2] anion-based ionic liquids on steel and PVD (TiN, CrN, ZrN) coatings

“…Some research groups focused their attention on thermophysical measurements (especially surface tension) of imidazolium-, pyridinium-, phosphonium-and ammonium-based ILs [19,[33][34][35].…”