Platinum group metals bulk analysis in automobile catalyst recycling material by laser-induced breakdown spectroscopy

Asimellis, George; Michos, Nikolaos; Fasaki, I.; Kompitsäs, M.

doi:10.1016/j.sab.2008.09.016

Cited by 32 publications

(12 citation statements)

References 35 publications

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“…The limit of detection was 50 ng•mL −1 at a signal-to-noise ratio of 3, with a large dynamic range that spanned approximately four orders of magnitude, which was comparable to that of previous methods used for platinum detection (Table S1). Currently, the detection of Pt in biological samples is often accomplished by analyzing the concentration of the element using inductively coupled plasmamass spectrometry (ICP-MS) [39][40][41]. Despite the high sensitivity, ICP-MS needs to be coupled with other separation techniques, which requires expensive instruments.…”

Section: Quantification Of Pt 2+ Ionsmentioning

confidence: 99%

A chemiluminescence resonance energy transfer strategy and its application for detection of platinum ions and cisplatin

Cai

Zhou

et al. 2019

Microchim Acta

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A novel chemiluminescence resonance energy transfer (CRET) system was developed and combined with a structureswitching aptamer for the highly sensitive detection of platinum. Platinum was chosen as a model analyte to demonstrate the generality of the new CRET system. This aptameric platform consisted of a streptavidin labeled aptamer against platinum and a streptavidin-coated magnetic bead for the selective separation of platinum-bound aptamer. The platinum-aptamer probe contained several guanine (G) bases bound to the 3,4,5-trimethoxyphenylglyoxal (TMPG) donor group at the 5′ end, a fluorescent acceptor (6-carboxy-2′,4,7,7′-tetrachlorofluorescein, TET) at the 3′ end, and a streptavidin aptamer sequence in which several base pairs were replaced by the G-G mismatch to induce the platinum-oligonucleotide coordination. The chemiluminescence (CL) generated by TMPG/G bases is transferred to the acceptor (TET). In the presence of platinum, the platinum-aptamer probe was folded such that the G bases at the 5′ end and TET at the 3′ were in close proximity. The complex was separated using streptavidincoated magnetic beads by the addition of TMPG to form the TMPG/G bases complex. The ultraweak CL from the TMPG/G bases was strongly enhanced by TET. This novel CRET-based method can be easily performed with high limit of detection (50 ng•mL −1 ) and selectivity over other metal ions. This technique provides a novel method for simple, fast, and convenient point-of-care diagnostics for monitoring proteins and metal ions.

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Section: Quantification Of Pt 2+ Ionsmentioning

confidence: 99%

A chemiluminescence resonance energy transfer strategy and its application for detection of platinum ions and cisplatin

Cai

Zhou

et al. 2019

Microchim Acta

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“…The use of catalytic converters [2] provides one of the solutions to the problem of minimising the dispersion of toxic compounds and lowering the amount of exhaust fumes emitted to the atmosphere during the combustion of fuels in passenger cars, trucks and buses, and many other types of machinery [3]. As most catalytic converters contain a combination of the three metals, Pt, Pd and Rh [4,5], the manufacture of catalysts for automobiles is the largest sector of demand for and consumption of PGMs (platinum group metals) [6][7][8]. Most studies and expert appraisals predict that future demand for these critical metals will increase [9].…”

Section: Introductionmentioning

confidence: 99%

Key Challenges and Opportunities for an Effective Supply Chain System in the Catalyst Recycling Market–A Case Study of Poland

Generowicz

Kulczycka

Partyka³

et al. 2021

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Increasing public awareness about low emission and stricter standards has a significant impact on the industry. The use of catalytic converters provides one of the solutions to the problem of lowering the amount of exhaust fumes. As most catalytic converters contain a combination of the three metals Pt, Pd and Rh, the manufacture of catalysts for automobiles is the largest sector of demand for and consumption of PGMs (platinum group metals). In Poland, the recycling system for catalysts is still in the development stage, but there is a significant trend of increase mainly due to EU policy on the circular economy. Due to frequent legal changes, the market is not fully transparent and the price for used catalysts can vary significantly. Therefore, apart from the recycling technology itself, it is important for the company to have a transparent method of testing the catalysts. The aim of this article was to identify the key opportunities and challenges to improving the catalyst recycling system in Poland. The organisational solutions have been analysed to show that an effective system could be implemented by creating a network between suppliers and customers with the use of good laboratory equipment and IT applications. The article defines the key opportunities and challenges such as the need to invest in an innovative laboratory and software for assessment of chemical composition and economic value of waste. A great opportunity for the development of this sector is the high demand for critical raw materials such as PGMs, which can be supported by research and development (R&D) projects.

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“…Such an approach permits to improve the sensitivity, considerably increases the sample throughput and reduces the risk of contamination/ losses. Thus, it is not surprising to see that different applications reporting on the determination of various PGMs by means of glow discharge mass spectrometry [8,9], laser ablation-ICP-MS [10][11][12][13][14] or optical emission spectrometry (OES) [15], electrothermal vaporization-ICP-MS [16,17], laser induced breakdown spectrometry [18,19] or X-ray fluorescence (XRF) [20][21][22] have been published. Obviously, only those techniques capable of providing a high sensitivity together with the maximum selectivity could be suited for this task.…”

Section: Introductionmentioning

confidence: 99%

Determination of palladium, platinum and rhodium in used automobile catalysts and active pharmaceutical ingredients using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis

Resano

Flórez

Queralt

et al. 2015

Spectrochimica Acta Part B: Atomic Spectroscopy

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Platinum group metals bulk analysis in automobile catalyst recycling material by laser-induced breakdown spectroscopy

Cited by 32 publications

References 35 publications

A chemiluminescence resonance energy transfer strategy and its application for detection of platinum ions and cisplatin

A chemiluminescence resonance energy transfer strategy and its application for detection of platinum ions and cisplatin

Key Challenges and Opportunities for an Effective Supply Chain System in the Catalyst Recycling Market–A Case Study of Poland

Determination of palladium, platinum and rhodium in used automobile catalysts and active pharmaceutical ingredients using high-resolution continuum source graphite furnace atomic absorption spectrometry and direct solid sample analysis

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